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@ARTICLE{Wolters:62964,
      author       = {Wolters, A. and Linnemann, V. and Smith, K.E.C. and
                      Klingelmann, E. and Park, B.J. and Vereecken, H.},
      title        = {{N}ovel chamber to measure equilibrium soil-air
                      partitioning coefficients of low-volatility organic
                      chemicals under conditions of varying temperature and soil
                      moisture},
      journal      = {Environmental Science $\&$ Technology},
      volume       = {42},
      issn         = {0013-936X},
      address      = {Columbus, Ohio},
      publisher    = {American Chemical Society},
      reportid     = {PreJuSER-62964},
      pages        = {4870 - 4876},
      year         = {2008},
      note         = {Record converted from VDB: 12.11.2012},
      abstract     = {The need to determine soil-air partitioning coefficients
                      (K-SA) of low-volatility organic chemicals as a measure of
                      their distribution in the soil surface after release into
                      the environment resulted in the development of a novel
                      chamber system, which has been filed for patent. A major
                      advantage of this pseudo-static system is that sufficient
                      time can be factored into the experiment to ensure that the
                      system has achieved equilibrium. In a highly precise method,
                      the air is collected in adsorption tubes and subsequently
                      liberated in a thermodesorption system for the quantitation
                      of the adsorbed compound. The precision of the method is
                      great enough that even the effects of temperature and soil
                      moisture on the soil-air partitioning of very low-volatility
                      compounds can be quantified. Because of analytical detection
                      limits, quantitation of these influences has not been
                      possible to date. Functionality of the setup was illustrated
                      by measurements on the fungicide fenpropimorph. K-SA values
                      of fenpropimorph displayed a negative relationship with
                      temperature and soil moisture. The type of application
                      (spraying or incorporation) and the use of formulated
                      compounds was shown to have a major impact on the measured
                      K-SA values. Comparison with calculations using an
                      estimation method revealed that the use of experimentally
                      determined K-SA values will facilitate a more adequate
                      consideration of volatilization in recent model approaches.},
      keywords     = {J (WoSType)},
      cin          = {ICG-4 / JARA-ENERGY / JARA-SIM},
      ddc          = {050},
      cid          = {I:(DE-Juel1)VDB793 / $I:(DE-82)080011_20140620$ /
                      I:(DE-Juel1)VDB1045},
      pnm          = {Terrestrische Umwelt},
      pid          = {G:(DE-Juel1)FUEK407},
      shelfmark    = {Engineering, Environmental / Environmental Sciences},
      typ          = {PUB:(DE-HGF)16},
      UT           = {WOS:000257220600045},
      doi          = {10.1021/es800372m},
      url          = {https://juser.fz-juelich.de/record/62964},
}