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024 7 _ |2 DOI
|a 10.1016/j.colsurfa.2008.05.012
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082 _ _ |a 540
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|a Chemistry, Physical
100 1 _ |a Klauth, P.
|b 0
|u FZJ
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245 _ _ |a Light fiber optic probe for measuring internal breakthrough of rare earth ion-labelled microspheres in porous media under unsaturated conditions
260 _ _ |a Amsterdam [u.a.]
|b Elsevier Science
|c 2008
300 _ _ |a 173 - 179
336 7 _ |a Journal Article
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336 7 _ |a article
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440 _ 0 |a Colloids and Surfaces A:Physicochemical and Engineering Aspects
|x 0927-7757
|0 1360
|y 3
|v 325
500 _ _ |a Record converted from VDB: 12.11.2012
520 _ _ |a Application of minimally invasive probes for measuring fluorescent labelled colloids inside sand columns resulted in internal breakthrough curves at given points, that provided information about mass distributions without disrupting the column. Until now, light fiber optic probes were used in combination with organic fluorophores like fluoresceine or rhodamine, which have inherent disadvantage, such as comparably small Stoke's shifts and quenching at high concentrations. These may be overcome using rare earth ion complexes to label colloidal particles like microspheres (MS). Furthermore, these dyes have large fluorescent lifetimes compared to organic fluorophores, which readily allows the elimination of background fluorescence using time-resolved spectroscopy. We demonstrate the novel application of rare earth ionlabelled microspheres as colloidal tracers in column experiments under unsaturated conditions in porous media in coupling with a detection setup based on internal light fiber optic probes. Differences in mass budgets between internal detection and detection at the outlet were confirmed afterwards by invasive refurbishment of the column matrix. (c) 2008 Elsevier B.V. All rights reserved.
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653 2 0 |2 Author
|a light fiber optic probe
653 2 0 |2 Author
|a rare earth ion-chelate complexes
653 2 0 |2 Author
|a microspheres
653 2 0 |2 Author
|a porous media
653 2 0 |2 Author
|a internal BTC
653 2 0 |2 Author
|a retention profile
653 2 0 |2 Author
|a unsaturated conditions
700 1 _ |a Joschko, A.
|b 1
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700 1 _ |a Ustohal, P.
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700 1 _ |a Büddefeld, J.
|b 3
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700 1 _ |a Klumpp, E.
|b 4
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700 1 _ |a Vereecken, H.
|b 5
|u FZJ
|0 P:(DE-Juel1)129549
700 1 _ |a Lezhnina, M.
|b 6
|0 P:(DE-HGF)0
700 1 _ |a Kynast, U.
|b 7
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773 _ _ |a 10.1016/j.colsurfa.2008.05.012
|g Vol. 325, p. 173 - 179
|p 173 - 179
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|0 PERI:(DE-600)1500517-3
|t Colloids and surfaces / A
|v 325
|y 2008
|x 0927-7757
856 7 _ |u http://dx.doi.org/10.1016/j.colsurfa.2008.05.012
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914 1 _ |y 2008
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