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@ARTICLE{Calandrini:6864,
author = {Calandrini, V. and Sutmann, G. and Deriu, A. and Kneller,
G.R.},
title = {{R}igid molecule approximation in memory function-based
models for molecular liquids: {A}pplication to liquid water},
journal = {Zeitschrift für Physikalische Chemie},
volume = {223},
issn = {0942-9352},
address = {München},
publisher = {Oldenbourg},
reportid = {PreJuSER-6864},
pages = {957 - 978},
year = {2009},
note = {Record converted from VDB: 12.11.2012},
abstract = {In the present article we show how models for simple
liquids can be used to describe the dynamics of atoms in
molecular liquids within the rigid molecule approximation.
We show in particular that the atomic masses are to be
replaced by the corresponding Sachs-Teller masses and we
derive a formal expression for the so-called Einstein
frequency. The approach is illustrated for a model which has
been originally developed for simple liquids and which has
been used in the past to analyze quasielastic neutron
scattering data from pure water and dilute aqueous solutions
of apolar molecules. We obtain a remarkable agreement with
results from molecular dynamics simulations not only in the
quasielastic, diffusive regime, but also in the inelastic
regime corresponding to intermolecular vibrations and fast
molecular librations.},
keywords = {J (WoSType)},
cin = {JSC},
ddc = {540},
cid = {I:(DE-Juel1)JSC-20090406},
pnm = {Scientific Computing},
pid = {G:(DE-Juel1)FUEK411},
shelfmark = {Chemistry, Physical},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000271326100003},
doi = {10.1524/zpch.2009.6063},
url = {https://juser.fz-juelich.de/record/6864},
}