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@ARTICLE{Zamponi:7863,
author = {Zamponi, M. and Pyckhout-Hintzen, W. and Wischnewski, A.
and Monkenbusch, M. and Willner, L. and Kali, G. and
Richter, D.},
title = {{M}olecular observation of branch point motion in star
polymer melts},
journal = {Macromolecules},
volume = {43},
number = {1},
issn = {0024-9297},
address = {Washington, DC},
publisher = {Soc.},
reportid = {PreJuSER-7863},
pages = {518 - 524},
year = {2010},
note = {Record converted from VDB: 12.11.2012},
abstract = {Using neutron spin echo (NSE) spectroscopy and a labeling
scheme unique to neutron scattering the motion of it labeled
branch point of a three-arm polyethylene star has been
observed oil a molecular level. The measured dynamic
structure factor shows a clear transition to a Plateau,
Signifying the stronger confinement of the star center in
comparison to a corresponding center labeled linear chain. A
shortening of one star arm to about only one entanglement
length leads to the same topological confinement as for the
symmetric star within the accessible time range of NSE. This
reflects it stronger effect of such it small branch than
expected and is consistent with rheological measurements on
the same system.},
keywords = {J (WoSType)},
cin = {IFF-5 / IFF-4 / Jülich Centre for Neutron Science JCNS
(JCNS) ; JCNS},
ddc = {540},
cid = {I:(DE-Juel1)VDB785 / I:(DE-Juel1)VDB784 /
I:(DE-Juel1)JCNS-20121112},
pnm = {BioSoft: Makromolekulare Systeme und biologische
Informationsverarbeitung / Großgeräte für die Forschung
mit Photonen, Neutronen und Ionen (PNI)},
pid = {G:(DE-Juel1)FUEK505 / G:(DE-Juel1)FUEK415},
shelfmark = {Polymer Science},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000273268700069},
doi = {10.1021/ma9017185},
url = {https://juser.fz-juelich.de/record/7863},
}