000808518 001__ 808518
000808518 005__ 20240712112838.0
000808518 0247_ $$2doi$$a10.1016/j.ceramint.2016.03.010
000808518 0247_ $$2ISSN$$a0272-8842
000808518 0247_ $$2ISSN$$a0392-2960
000808518 0247_ $$2WOS$$aWOS:000374811600020
000808518 037__ $$aFZJ-2016-02258
000808518 082__ $$a670
000808518 1001_ $$0P:(DE-Juel1)141800$$aRöhrens, Daniel$$b0$$eCorresponding author
000808518 245__ $$aFormation of chromium containing impurities in (La,Sr)MnO$_{3}$ solid-oxide-fuel-cell cathodes under stack operating conditions and its effect on performance
000808518 260__ $$aAmsterdam [u.a.]$$bElsevier Science$$c2016
000808518 3367_ $$0PUB:(DE-HGF)16$$2PUB:(DE-HGF)$$aJournal Article$$bjournal$$mjournal$$s1460612457_2944
000808518 3367_ $$2DataCite$$aOutput Types/Journal article
000808518 3367_ $$00$$2EndNote$$aJournal Article
000808518 3367_ $$2BibTeX$$aARTICLE
000808518 3367_ $$2ORCID$$aJOURNAL_ARTICLE
000808518 3367_ $$2DRIVER$$aarticle
000808518 520__ $$aIn this study, we present an investigation of the chromium-related electrical performance degradation of anode-supported SOFCs with a LSM/YSZ composite cathode. A traditional ferritic interconnect steel with high chromium content is established as the primary chromium source and chromium poisoning of the cathode is carried out at relevant SOFC operating conditions. The prolonged influence of the gaseous chromium species on the cell performance and cathode microstructure under constant current conditions was examined quantitatively. Physical deposition of chromium(III) compounds (mainly spinel-type (Cr,Mn)3O4 phases) was observed at the electrochemically active region adjacent to the electrolyte only under realistic constant current conditions. The microstructural degradation associated with the formation of secondary phases correlated directly with the performance degradation, the effective chromium partial pressure and the current density. Furthermore, the influence of the presence of a number of protecting layers on the interconnect steel was evaluated with regard to the cathode poisoning. It was shown that chromium-induced degradation was reduced drastically when an additional manganese reservoir layer and a Cr getter layer were applied.
000808518 536__ $$0G:(DE-HGF)POF3-135$$a135 - Fuel Cells (POF3-135)$$cPOF3-135$$fPOF III$$x0
000808518 536__ $$0G:(DE-Juel1)SOFC-20140602$$aSOFC - Solid Oxide Fuel Cell (SOFC-20140602)$$cSOFC-20140602$$fSOFC$$x1
000808518 536__ $$0G:(DE-Juel1)HITEC-20170406$$aHITEC - Helmholtz Interdisciplinary Doctoral Training in Energy and Climate Research (HITEC) (HITEC-20170406)$$cHITEC-20170406$$x2
000808518 588__ $$aDataset connected to CrossRef
000808518 7001_ $$0P:(DE-HGF)0$$aNeumann, A.$$b1
000808518 7001_ $$0P:(DE-Juel1)165688$$aBeez, A.$$b2$$ufzj
000808518 7001_ $$0P:(DE-Juel1)129936$$aVinke, I. C.$$b3$$ufzj
000808518 7001_ $$0P:(DE-Juel1)129952$$ade Haart, L.G.J.$$b4$$ufzj
000808518 7001_ $$0P:(DE-Juel1)129636$$aMenzler, N. H.$$b5$$ufzj
000808518 773__ $$0PERI:(DE-600)2018052-4$$a10.1016/j.ceramint.2016.03.010$$gVol. 42, no. 8, p. 9467 - 9474$$n8$$p9467 - 9474$$tCeramics international$$v42$$x0272-8842$$y2016
000808518 8564_ $$uhttps://juser.fz-juelich.de/record/808518/files/1-s2.0-S0272884216301316-main.pdf$$yRestricted
000808518 8564_ $$uhttps://juser.fz-juelich.de/record/808518/files/1-s2.0-S0272884216301316-main.gif?subformat=icon$$xicon$$yRestricted
000808518 8564_ $$uhttps://juser.fz-juelich.de/record/808518/files/1-s2.0-S0272884216301316-main.jpg?subformat=icon-1440$$xicon-1440$$yRestricted
000808518 8564_ $$uhttps://juser.fz-juelich.de/record/808518/files/1-s2.0-S0272884216301316-main.jpg?subformat=icon-180$$xicon-180$$yRestricted
000808518 8564_ $$uhttps://juser.fz-juelich.de/record/808518/files/1-s2.0-S0272884216301316-main.jpg?subformat=icon-640$$xicon-640$$yRestricted
000808518 8564_ $$uhttps://juser.fz-juelich.de/record/808518/files/1-s2.0-S0272884216301316-main.pdf?subformat=pdfa$$xpdfa$$yRestricted
000808518 909CO $$ooai:juser.fz-juelich.de:808518$$pVDB
000808518 9101_ $$0I:(DE-588b)5008462-8$$6P:(DE-Juel1)141800$$aForschungszentrum Jülich GmbH$$b0$$kFZJ
000808518 9101_ $$0I:(DE-588b)5008462-8$$6P:(DE-Juel1)165688$$aForschungszentrum Jülich GmbH$$b2$$kFZJ
000808518 9101_ $$0I:(DE-588b)5008462-8$$6P:(DE-Juel1)129936$$aForschungszentrum Jülich GmbH$$b3$$kFZJ
000808518 9101_ $$0I:(DE-588b)5008462-8$$6P:(DE-Juel1)129952$$aForschungszentrum Jülich GmbH$$b4$$kFZJ
000808518 9101_ $$0I:(DE-588b)5008462-8$$6P:(DE-Juel1)129636$$aForschungszentrum Jülich GmbH$$b5$$kFZJ
000808518 9131_ $$0G:(DE-HGF)POF3-135$$1G:(DE-HGF)POF3-130$$2G:(DE-HGF)POF3-100$$3G:(DE-HGF)POF3$$4G:(DE-HGF)POF$$aDE-HGF$$bEnergie$$lSpeicher und vernetzte Infrastrukturen$$vFuel Cells$$x0
000808518 9141_ $$y2016
000808518 915__ $$0StatID:(DE-HGF)0200$$2StatID$$aDBCoverage$$bSCOPUS
000808518 915__ $$0StatID:(DE-HGF)1160$$2StatID$$aDBCoverage$$bCurrent Contents - Engineering, Computing and Technology
000808518 915__ $$0StatID:(DE-HGF)0100$$2StatID$$aJCR$$bCERAM INT : 2014
000808518 915__ $$0StatID:(DE-HGF)0150$$2StatID$$aDBCoverage$$bWeb of Science Core Collection
000808518 915__ $$0StatID:(DE-HGF)0110$$2StatID$$aWoS$$bScience Citation Index
000808518 915__ $$0StatID:(DE-HGF)0111$$2StatID$$aWoS$$bScience Citation Index Expanded
000808518 915__ $$0StatID:(DE-HGF)9900$$2StatID$$aIF < 5
000808518 915__ $$0StatID:(DE-HGF)1150$$2StatID$$aDBCoverage$$bCurrent Contents - Physical, Chemical and Earth Sciences
000808518 915__ $$0StatID:(DE-HGF)0300$$2StatID$$aDBCoverage$$bMedline
000808518 915__ $$0StatID:(DE-HGF)0550$$2StatID$$aNo Authors Fulltext
000808518 915__ $$0StatID:(DE-HGF)0199$$2StatID$$aDBCoverage$$bThomson Reuters Master Journal List
000808518 920__ $$lyes
000808518 9201_ $$0I:(DE-Juel1)IEK-1-20101013$$kIEK-1$$lWerkstoffsynthese und Herstellungsverfahren$$x0
000808518 9201_ $$0I:(DE-Juel1)IEK-9-20110218$$kIEK-9$$lGrundlagen der Elektrochemie$$x1
000808518 980__ $$ajournal
000808518 980__ $$aVDB
000808518 980__ $$aUNRESTRICTED
000808518 980__ $$aI:(DE-Juel1)IEK-1-20101013
000808518 980__ $$aI:(DE-Juel1)IEK-9-20110218
000808518 981__ $$aI:(DE-Juel1)IET-1-20110218
000808518 981__ $$aI:(DE-Juel1)IMD-2-20101013
000808518 981__ $$aI:(DE-Juel1)IEK-9-20110218