guest ::
| Home > Publications database > Time-of-flight secondary ion mass spectrometry study of lithium intercalation process in LiCoO$_2$ thin film > print |
| Home > Publications database > Time-of-flight secondary ion mass spectrometry study of lithium intercalation process in LiCoO$_2$ thin film > print |
| 001 | 809434 | ||
| 005 | 20240711114029.0 | ||
| 024 | 7 | _ | |a 10.1016/j.jpowsour.2016.04.084 |2 doi |
| 024 | 7 | _ | |a 2128/11201 |2 Handle |
| 024 | 7 | _ | |a WOS:000377729200027 |2 WOS |
| 037 | _ | _ | |a FZJ-2016-02540 |
| 082 | _ | _ | |a 620 |
| 100 | 1 | _ | |a Dellen, Christian |0 P:(DE-Juel1)158085 |b 0 |e Corresponding author |u fzj |
| 245 | _ | _ | |a Time-of-flight secondary ion mass spectrometry study of lithium intercalation process in LiCoO$_2$ thin film |
| 260 | _ | _ | |a New York, NY [u.a.] |c 2016 |b Elsevier |
| 336 | 7 | _ | |a article |2 DRIVER |
| 336 | 7 | _ | |a Output Types/Journal article |2 DataCite |
| 336 | 7 | _ | |a Journal Article |b journal |m journal |0 PUB:(DE-HGF)16 |s 1487341958_19081 |2 PUB:(DE-HGF) |
| 336 | 7 | _ | |a ARTICLE |2 BibTeX |
| 336 | 7 | _ | |a JOURNAL_ARTICLE |2 ORCID |
| 336 | 7 | _ | |a Journal Article |0 0 |2 EndNote |
| 520 | _ | _ | |a A detailed time-of-flight secondary ion mass spectrometry (ToF-SIMS) analysis of the lithium de-/intercalation in thin films of the insertion cathode material lithium cobalt oxide is presented. The LiCoO2 (LCO) thin films are deposited by radio frequency magnetron sputtering at 600 °C, having a (003) preferred orientation after the deposition. The thin electrode films are cycled with liquid electrolyte against lithium metal, showing 80-86% extractable capacities. After disassembling the cells, the depth resolved elemental distribution in the LCO is investigated by ToF-SIMS and glow discharge optical emission spectroscopy. Both techniques show a stepwise lithium distribution in charged state, leading to a lithium depleted layer close to the surface. In combination with the electrochemical results, the qualitative comparison of the different lithium depth profiles yields a reversible lithium extraction in the depleted area below the stability limit for bulk materials of LCO. For bulk LCO, a phase change normally occurs when the lithium concentration in LixCoO2 is lower than x=0.5. As a possible cause for the inhibition of the phase change, the preferred orientation and thus pinning of the crystal structure of the film by the substrate is proposed. |
| 536 | _ | _ | |a 113 - Methods and Concepts for Material Development (POF3-113) |0 G:(DE-HGF)POF3-113 |c POF3-113 |f POF III |x 0 |
| 536 | _ | _ | |0 G:(DE-Juel1)HITEC-20170406 |x 1 |c HITEC-20170406 |a HITEC - Helmholtz Interdisciplinary Doctoral Training in Energy and Climate Research (HITEC) (HITEC-20170406) |
| 700 | 1 | _ | |a Gehrke, Hans-Gregor |0 P:(DE-Juel1)162280 |b 1 |u fzj |
| 700 | 1 | _ | |a Möller, Sören |0 P:(DE-Juel1)139534 |b 2 |u fzj |
| 700 | 1 | _ | |a Tsai, Chih-Long |0 P:(DE-Juel1)156244 |b 3 |u fzj |
| 700 | 1 | _ | |a Breuer, Uwe |0 P:(DE-Juel1)133840 |b 4 |u fzj |
| 700 | 1 | _ | |a Uhlenbruck, Sven |0 P:(DE-Juel1)129580 |b 5 |u fzj |
| 700 | 1 | _ | |a Guillon, Olivier |0 P:(DE-Juel1)161591 |b 6 |u fzj |
| 700 | 1 | _ | |a Finsterbusch, Martin |0 P:(DE-Juel1)145623 |b 7 |u fzj |
| 700 | 1 | _ | |a Bram, Martin |0 P:(DE-Juel1)129591 |b 8 |u fzj |
| 773 | _ | _ | |a 10.1016/j.jpowsour.2016.04.084 |0 PERI:(DE-600)1491915-1 |p 241-247 |t Journal of power sources |v 321 |y 2016 |x 0378-7753 |
| 856 | 4 | _ | |u https://juser.fz-juelich.de/record/809434/files/Time-of-flight%20secondary%20ion%20mass%20spectrometry%20study%20of%20lithium%20intercalation%20process%20in%20LiCoO2%20thin%20film.pdf |y OpenAccess |z StatID:(DE-HGF)0510 |
| 856 | 4 | _ | |u https://juser.fz-juelich.de/record/809434/files/Time-of-flight%20secondary%20ion%20mass%20spectrometry%20study%20of%20lithium%20intercalation%20process%20in%20LiCoO2%20thin%20film.gif?subformat=icon |x icon |y OpenAccess |z StatID:(DE-HGF)0510 |
| 856 | 4 | _ | |u https://juser.fz-juelich.de/record/809434/files/Time-of-flight%20secondary%20ion%20mass%20spectrometry%20study%20of%20lithium%20intercalation%20process%20in%20LiCoO2%20thin%20film.jpg?subformat=icon-1440 |x icon-1440 |y OpenAccess |z StatID:(DE-HGF)0510 |
| 856 | 4 | _ | |u https://juser.fz-juelich.de/record/809434/files/Time-of-flight%20secondary%20ion%20mass%20spectrometry%20study%20of%20lithium%20intercalation%20process%20in%20LiCoO2%20thin%20film.jpg?subformat=icon-180 |x icon-180 |y OpenAccess |z StatID:(DE-HGF)0510 |
| 856 | 4 | _ | |u https://juser.fz-juelich.de/record/809434/files/Time-of-flight%20secondary%20ion%20mass%20spectrometry%20study%20of%20lithium%20intercalation%20process%20in%20LiCoO2%20thin%20film.jpg?subformat=icon-640 |x icon-640 |y OpenAccess |z StatID:(DE-HGF)0510 |
| 856 | 4 | _ | |u https://juser.fz-juelich.de/record/809434/files/Time-of-flight%20secondary%20ion%20mass%20spectrometry%20study%20of%20lithium%20intercalation%20process%20in%20LiCoO2%20thin%20film.pdf?subformat=pdfa |x pdfa |y OpenAccess |z StatID:(DE-HGF)0510 |
| 909 | C | O | |o oai:juser.fz-juelich.de:809434 |p openaire |p driver |p open_access |p VDB |p dnbdelivery |
| 910 | 1 | _ | |a Forschungszentrum Jülich |0 I:(DE-588b)5008462-8 |k FZJ |b 0 |6 P:(DE-Juel1)158085 |
| 910 | 1 | _ | |a Forschungszentrum Jülich |0 I:(DE-588b)5008462-8 |k FZJ |b 1 |6 P:(DE-Juel1)162280 |
| 910 | 1 | _ | |a Forschungszentrum Jülich |0 I:(DE-588b)5008462-8 |k FZJ |b 2 |6 P:(DE-Juel1)139534 |
| 910 | 1 | _ | |a Forschungszentrum Jülich |0 I:(DE-588b)5008462-8 |k FZJ |b 3 |6 P:(DE-Juel1)156244 |
| 910 | 1 | _ | |a Forschungszentrum Jülich |0 I:(DE-588b)5008462-8 |k FZJ |b 4 |6 P:(DE-Juel1)133840 |
| 910 | 1 | _ | |a Forschungszentrum Jülich |0 I:(DE-588b)5008462-8 |k FZJ |b 5 |6 P:(DE-Juel1)129580 |
| 910 | 1 | _ | |a Forschungszentrum Jülich |0 I:(DE-588b)5008462-8 |k FZJ |b 6 |6 P:(DE-Juel1)161591 |
| 910 | 1 | _ | |a Forschungszentrum Jülich |0 I:(DE-588b)5008462-8 |k FZJ |b 7 |6 P:(DE-Juel1)145623 |
| 910 | 1 | _ | |a Forschungszentrum Jülich |0 I:(DE-588b)5008462-8 |k FZJ |b 8 |6 P:(DE-Juel1)129591 |
| 913 | 1 | _ | |a DE-HGF |l Energieeffizienz, Materialien und Ressourcen |1 G:(DE-HGF)POF3-110 |0 G:(DE-HGF)POF3-113 |2 G:(DE-HGF)POF3-100 |v Methods and Concepts for Material Development |x 0 |4 G:(DE-HGF)POF |3 G:(DE-HGF)POF3 |b Energie |
| 914 | 1 | _ | |y 2016 |
| 915 | _ | _ | |a DBCoverage |0 StatID:(DE-HGF)0200 |2 StatID |b SCOPUS |
| 915 | _ | _ | |a DBCoverage |0 StatID:(DE-HGF)1160 |2 StatID |b Current Contents - Engineering, Computing and Technology |
| 915 | _ | _ | |a JCR |0 StatID:(DE-HGF)0100 |2 StatID |b J POWER SOURCES : 2014 |
| 915 | _ | _ | |a IF >= 5 |0 StatID:(DE-HGF)9905 |2 StatID |b J POWER SOURCES : 2014 |
| 915 | _ | _ | |a DBCoverage |0 StatID:(DE-HGF)0150 |2 StatID |b Web of Science Core Collection |
| 915 | _ | _ | |a WoS |0 StatID:(DE-HGF)0110 |2 StatID |b Science Citation Index |
| 915 | _ | _ | |a WoS |0 StatID:(DE-HGF)0111 |2 StatID |b Science Citation Index Expanded |
| 915 | _ | _ | |a OpenAccess |0 StatID:(DE-HGF)0510 |2 StatID |
| 915 | _ | _ | |a DBCoverage |0 StatID:(DE-HGF)1150 |2 StatID |b Current Contents - Physical, Chemical and Earth Sciences |
| 915 | _ | _ | |a DBCoverage |0 StatID:(DE-HGF)0310 |2 StatID |b NCBI Molecular Biology Database |
| 915 | _ | _ | |a DBCoverage |0 StatID:(DE-HGF)0300 |2 StatID |b Medline |
| 915 | _ | _ | |a DBCoverage |0 StatID:(DE-HGF)0199 |2 StatID |b Thomson Reuters Master Journal List |
| 920 | _ | _ | |l yes |
| 920 | 1 | _ | |0 I:(DE-Juel1)IEK-1-20101013 |k IEK-1 |l Werkstoffsynthese und Herstellungsverfahren |x 0 |
| 920 | 1 | _ | |0 I:(DE-82)080011_20140620 |k JARA-ENERGY |l JARA-ENERGY |x 1 |
| 920 | 1 | _ | |0 I:(DE-Juel1)IEK-4-20101013 |k IEK-4 |l Plasmaphysik |x 2 |
| 920 | 1 | _ | |0 I:(DE-Juel1)ZEA-3-20090406 |k ZEA-3 |l Analytik |x 3 |
| 980 | 1 | _ | |a FullTexts |
| 980 | _ | _ | |a journal |
| 980 | _ | _ | |a VDB |
| 980 | _ | _ | |a I:(DE-Juel1)IEK-1-20101013 |
| 980 | _ | _ | |a I:(DE-82)080011_20140620 |
| 980 | _ | _ | |a I:(DE-Juel1)IEK-4-20101013 |
| 980 | _ | _ | |a I:(DE-Juel1)ZEA-3-20090406 |
| 980 | _ | _ | |a UNRESTRICTED |
| 981 | _ | _ | |a I:(DE-Juel1)IFN-1-20101013 |
| 981 | _ | _ | |a I:(DE-Juel1)IMD-2-20101013 |
| 981 | _ | _ | |a I:(DE-Juel1)IEK-4-20101013 |
| 981 | _ | _ | |a I:(DE-Juel1)ZEA-3-20090406 |
| Library | Collection | CLSMajor | CLSMinor | Language | Author |
|---|