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@ARTICLE{Kao:809770,
      author       = {Kao, Yu-Ju and Su, Che-Yi and Pithan, Christian and
                      Hennings, Detlev and Huang, Chi-Yuen and Waser, R.},
      title        = {{H}ydroxyl {D}efect {E}ffect on {R}eoxidation of
                      {S}c-{D}oped ({B}a,{C}a)({T}i,{Z}r){O} 3 {F}ired in
                      {R}educing {A}tmospheres},
      journal      = {Journal of the American Ceramic Society},
      volume       = {99},
      number       = {4},
      issn         = {0002-7820},
      address      = {Oxford [u.a.]},
      publisher    = {Wiley-Blackwell},
      reportid     = {FZJ-2016-02697},
      pages        = {1311 - 1317},
      year         = {2016},
      abstract     = {The behavior of grain and grain-boundary conductivity of
                      acceptor (Sc)-doped (Ba,Ca)(Ti,Zr)O3 ceramics sintered in
                      moist reducing atmosphere and subsequently reoxidized in dry
                      and moist atmosphere was investigated by means of impedance
                      spectroscopy (IS). In moist firing atmosphere, water vapor
                      was found to react with oxygen vacancies, forming positively
                      charged hydroxyl defects inline image on regular oxygen
                      sites in the crystal lattice. Proton hopping is considered
                      to raise the ionic conductivity significantly. Therefore,
                      hydroxyl defects inline image in turn influence the grain
                      conduction. Hydroxyl defects inline image are also
                      considered to be responsible for alternations of the
                      dielectric maximum at the Curie point.},
      cin          = {PGI-7},
      ddc          = {660},
      cid          = {I:(DE-Juel1)PGI-7-20110106},
      pnm          = {524 - Controlling Collective States (POF3-524)},
      pid          = {G:(DE-HGF)POF3-524},
      typ          = {PUB:(DE-HGF)16},
      UT           = {WOS:000373931900032},
      doi          = {10.1111/jace.14092},
      url          = {https://juser.fz-juelich.de/record/809770},
}