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@ARTICLE{Schlag:810108,
author = {Schlag, P. and Kiendler-Scharr, A. and Blom, M. J. and
Canonaco, F. and Henzing, J. S. and Moerman, M. M. and
Prévôt, A. S. H. and Holzinger, R.},
title = {{A}erosol source apportionment from 1 year measurements at
the {CESAR} tower at {C}abauw, {NL}},
journal = {Atmospheric chemistry and physics / Discussions},
volume = {15},
number = {23},
issn = {1680-7375},
address = {Katlenburg-Lindau},
publisher = {EGU},
reportid = {FZJ-2016-02983},
pages = {35117 - 35155},
year = {2015},
abstract = {Intensive measurements of submicron aerosol particles and
their chemical composition were performed with an Aerosol
Chemical Speciation Monitor (ACSM) at the Cabauw
Experimental Site for Atmospheric Research (CESAR) in
Cabauw, NL. The campaign lasted nearly one year from July
2012 to June 2013 as part of the ACTRIS project. Including
black carbon data an average particulate mass concentration
of 9.50 μg m−3 was obtained during the whole campaign
with dominant contributions from ammonium nitrate (45 $\%),$
organic aerosol (OA, 29 $\%),$ and ammonium sulfate (19
$\%).$ 12 exceedances of the World Health Organization (WHO)
PM2.5 daily mean limit (25 μg m−3) were observed at this
rural site using PM1 instrumentation only. Ammonium nitrate
and OA represented the largest contributors to total
particulate matter during periods of exceedance.Source
apportionment of OA was performed season-wise by Positive
Matrix Factorization (PMF) using the Multilinear Engine 2
(ME-2) controlled via the source finder (SoFi). Primary
organic aerosols were attributed mainly to traffic (8–16
$\%$ contribution to total OA, averaged season-wise) and
biomass burning (0–23 $\%).$ Secondary organic aerosols
(SOA, 61–84 $\%)$ dominated the organic fraction during
the whole campaign, particularly on days with high mass
loadings. A SOA factor which is attributed to humic-like
substances (HULIS) was identified as a highly oxidized
background aerosol in Cabauw. This shows the importance of
atmospheric ageing processes for aerosol concentration at
this rural site. Due to the large secondary fraction, the
reduction of particulate mass at this rural site is
challenging on a local scale.},
cin = {IEK-8},
ddc = {550},
cid = {I:(DE-Juel1)IEK-8-20101013},
pnm = {243 - Tropospheric trace substances and their
transformation processes (POF3-243)},
pid = {G:(DE-HGF)POF3-243},
typ = {PUB:(DE-HGF)16},
doi = {10.5194/acpd-15-35117-2015},
url = {https://juser.fz-juelich.de/record/810108},
}