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@ARTICLE{Marcano:810170,
      author       = {Marcano, D. and Mauer, G. and Sohn, Y. J. and Vassen,
                      Robert and Garcia-Fayos, J. and Serra, J. M.},
      title        = {{T}he {R}ole of {O}xygen {P}artial {P}ressure in
                      {C}ontrolling the {P}hase {C}omposition of {L}a$_{1−x}$
                      {S}r $_{x}$ {C}o $_{y}$ {F}e$_{1−y}$ {O}$_{3−δ}$
                      {O}xygen {T}ransport {M}embranes {M}anufactured by {M}eans
                      of {P}lasma {S}pray-{P}hysical {V}apor {D}eposition},
      journal      = {Journal of thermal spray technology},
      volume       = {25},
      number       = {4},
      issn         = {1544-1016},
      address      = {Boston, Mass.},
      publisher    = {Springer},
      reportid     = {FZJ-2016-03045},
      pages        = {631 - 638},
      year         = {2016},
      abstract     = {La0.58Sr0.4Co0.2Fe0.8O3− δ (LSCF) deposited on a
                      metallic porous support by plasma spray-physical vapor
                      deposition is a promising candidate for oxygen-permeation
                      membranes. Ionic transport properties are regarded to depend
                      on the fraction of perovskite phase present in the membrane.
                      However, during processing, the LSCF powder decomposes into
                      perovskite and secondary phases. In order to improve the
                      ionic transport properties of the membranes, spraying was
                      carried out at different oxygen partial pressures p(O2). It
                      was found that coatings deposited at lower and higher oxygen
                      partial pressures consist of $70\%$ $cubic/26\%$
                      rhombohedral and $61\%$ $cubic/35\%$ rhombohedral perovskite
                      phases, respectively. During annealing, the formation of
                      non-perovskite phases is driven by oxygen non-stoichiometry.
                      The amount of oxygen added during spraying can be used to
                      increase the perovskite phase fraction and suppress the
                      formation of non-perovskite phases},
      cin          = {IEK-1},
      ddc          = {670},
      cid          = {I:(DE-Juel1)IEK-1-20101013},
      pnm          = {113 - Methods and Concepts for Material Development
                      (POF3-113)},
      pid          = {G:(DE-HGF)POF3-113},
      typ          = {PUB:(DE-HGF)16},
      UT           = {WOS:000374328500003},
      doi          = {10.1007/s11666-016-0383-y},
      url          = {https://juser.fz-juelich.de/record/810170},
}