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000810538 1001_ $$0P:(DE-Juel1)8833$$aSang, X. F.$$b0$$ufzj
000810538 245__ $$aChemical stability of levoglucosan: An isotopic perspective
000810538 260__ $$aHoboken, NJ$$bWiley$$c2016
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000810538 520__ $$aThe chemical stability of levoglucosan was studied by exploring its isotopic fractionation during the oxidation by hydroxyl radicals. Aqueous solutions as well as mixed (NH4)2SO4-levoglucosan particles were exposed to OH. In both cases, samples experiencing different extents of processing were isotopically analyzed by Thermal Desorption-Gas Chromatography-Isotope Ratio Mass Spectrometry (TD-GC-IRMS). From the dependence of levoglucosan δ13C and concentration on the reaction extent, the kinetic isotope effect (KIE) of the OH oxidation reactions was determined to be 1.00187±0.00027 and 1.00229±0.00018, respectively. Both show good agreement within the uncertainty range. For the heterogeneous oxidation of particulate levoglucosan by gas-phase OH, a reaction rate constant of (2.67±0.03)·10−12 cm3 molecule−1S−1 was derived. The laboratory kinetic data, together with isotopic source and ambient observations, give information on the extent of aerosol chemical processing in the atmosphere.
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000810538 7001_ $$0P:(DE-Juel1)6110$$aGensch, I.$$b1$$eCorresponding author$$ufzj
000810538 7001_ $$0P:(DE-Juel1)129212$$aKammer, B.$$b2$$ufzj
000810538 7001_ $$0P:(DE-Juel1)165652$$aKhan, A.$$b3$$ufzj
000810538 7001_ $$0P:(DE-Juel1)129345$$aKleist, E.$$b4$$ufzj
000810538 7001_ $$0P:(DE-Juel1)129220$$aLaumer, W.$$b5$$ufzj
000810538 7001_ $$0P:(DE-Juel1)4548$$aSchlag, P.$$b6$$ufzj
000810538 7001_ $$0P:(DE-Juel1)161557$$aSchmitt, Sebastian$$b7$$ufzj
000810538 7001_ $$0P:(DE-Juel1)129421$$aWildt, J.$$b8$$ufzj
000810538 7001_ $$0P:(DE-HGF)0$$aZhao, R.$$b9
000810538 7001_ $$0P:(DE-HGF)0$$aMungall, E. L.$$b10
000810538 7001_ $$0P:(DE-HGF)0$$aAbbatt, J. P. D.$$b11
000810538 7001_ $$0P:(DE-Juel1)4528$$aKiendler-Scharr, A.$$b12$$ufzj
000810538 773__ $$0PERI:(DE-600)2021599-X$$a10.1002/2016GL069179$$gVol. 43, no. 10, p. 5419 - 5424$$n10$$p5419 - 5424$$tGeophysical research letters$$v43$$x0094-8276$$y2016
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