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| Home > Publications database > Chemical stability of levoglucosan: An isotopic perspective > print |
| 001 | 810538 | ||
| 005 | 20240712101037.0 | ||
| 024 | 7 | _ | |a 10.1002/2016GL069179 |2 doi |
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| 100 | 1 | _ | |a Sang, X. F. |0 P:(DE-Juel1)8833 |b 0 |u fzj |
| 245 | _ | _ | |a Chemical stability of levoglucosan: An isotopic perspective |
| 260 | _ | _ | |a Hoboken, NJ |c 2016 |b Wiley |
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| 520 | _ | _ | |a The chemical stability of levoglucosan was studied by exploring its isotopic fractionation during the oxidation by hydroxyl radicals. Aqueous solutions as well as mixed (NH4)2SO4-levoglucosan particles were exposed to OH. In both cases, samples experiencing different extents of processing were isotopically analyzed by Thermal Desorption-Gas Chromatography-Isotope Ratio Mass Spectrometry (TD-GC-IRMS). From the dependence of levoglucosan δ13C and concentration on the reaction extent, the kinetic isotope effect (KIE) of the OH oxidation reactions was determined to be 1.00187±0.00027 and 1.00229±0.00018, respectively. Both show good agreement within the uncertainty range. For the heterogeneous oxidation of particulate levoglucosan by gas-phase OH, a reaction rate constant of (2.67±0.03)·10−12 cm3 molecule−1S−1 was derived. The laboratory kinetic data, together with isotopic source and ambient observations, give information on the extent of aerosol chemical processing in the atmosphere. |
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| 700 | 1 | _ | |a Gensch, I. |0 P:(DE-Juel1)6110 |b 1 |e Corresponding author |u fzj |
| 700 | 1 | _ | |a Kammer, B. |0 P:(DE-Juel1)129212 |b 2 |u fzj |
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| 700 | 1 | _ | |a Kiendler-Scharr, A. |0 P:(DE-Juel1)4528 |b 12 |u fzj |
| 773 | _ | _ | |a 10.1002/2016GL069179 |g Vol. 43, no. 10, p. 5419 - 5424 |0 PERI:(DE-600)2021599-X |n 10 |p 5419 - 5424 |t Geophysical research letters |v 43 |y 2016 |x 0094-8276 |
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