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@ARTICLE{Kaiser:810763,
      author       = {Kaiser, A. and Foghmoes, S. and Pecanac, G. and Malzbender,
                      Jürgen and Chatzichristodoulou, C. and Glasscock, J. A. and
                      Ramachandran, D. and Ni, D. W. and Esposito, V. and Sogaard,
                      M. and Hendriksen, P. V.},
      title        = {{D}esign and {O}ptimisation of {P}orous {S}upports for
                      {A}symmetric {C}eria-{B}ased {O}xygen {T}ransport
                      {M}embranes},
      journal      = {Journal of membrane science},
      volume       = {513},
      issn         = {0376-7388},
      address      = {New York, NY [u.a.]},
      publisher    = {Elsevier},
      reportid     = {FZJ-2016-03352},
      pages        = {85-94},
      year         = {2016},
      abstract     = {The microstructure, mechanical properties and gas
                      permeability of porous supports of Ce0.9Gd0.1O1.95−δ
                      (CGO) were investigated as a function of sintering
                      temperature and volume fraction of pore former for use in
                      planar asymmetric oxygen transport membranes (OTMs). With
                      increasing the pore former content from 11 $vol\%$ to 16
                      $vol\%,$ the gas permeabilities increased by a factor of 5
                      when support tapes were sintered to comparable densities.
                      The improved permeabilities were due to a more favourable
                      microstructure with larger interconnected pores at a
                      porosity of $45\%$ and a fracture strength of 47±2 MPa
                      (m=7). The achieved gas permeability of 2.25×10−15 m2 for
                      a 0.4 mm thick support will not limit the gas transport for
                      oxygen production but in partial oxidation of methane to
                      syngas at higher oxygen fluxes. For integration of the CGO
                      support layer into a flat, asymmetric CGO membrane, the
                      sintering activity of the CGO membrane was reduced by Fe2O3
                      addition (replacing Co3O4 as sintering additive).},
      cin          = {IEK-2},
      ddc          = {570},
      cid          = {I:(DE-Juel1)IEK-2-20101013},
      pnm          = {111 - Efficient and Flexible Power Plants (POF3-111)},
      pid          = {G:(DE-HGF)POF3-111},
      typ          = {PUB:(DE-HGF)16},
      UT           = {WOS:000376301400010},
      doi          = {10.1016/j.memsci.2016.04.016},
      url          = {https://juser.fz-juelich.de/record/810763},
}