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@ARTICLE{Yu:810888,
author = {Yu, Shicheng and Tempel, Hermann and Schierholz, Roland and
Aslanbas, Özgür and Mertens, Josef and Gao, Xin and de
Haart, L. G. J. and Kungl, Hans and Eichel, Rüdiger-A.},
title = {{L}i{T}i$_{2}$({PO}$_{4}$)$_{3}$/{C} {A}node {M}aterial
with a {S}pindle-{L}ike {M}orphology for {B}atteries with
{H}igh {R}ate {C}apability and {I}mproved {C}ycle {L}ife},
journal = {ChemElectroChem},
volume = {3},
number = {7},
issn = {2196-0216},
address = {Weinheim},
publisher = {Wiley-VCH},
reportid = {FZJ-2016-03462},
pages = {1157-1169},
year = {2016},
abstract = {Nanocrystalline LiTi2(PO4)3/C has been synthesized by
employing a solvothermal process in which oxalic acid was
used as a solubilizer for the titanium source, a surfactant,
and a carbon source. Additionally, Pechini's sol–gel-based
method was also used as the synthesis method for comparison.
LiTi2(PO4)3/C prepared by using a solvothermal route showed
a homogenous particle size with spindle-like microstructures
formed from self-assembled nanosized-platelets, whereas
preparation by the sol–gel process resulted in
agglomerated powders with irregular morphology and particle
size. The different morphologies of LiTi2(PO4)3/C prepared
in the two synthesis methods tend to form different
electrode layer structures, which results in remarkable
differences in their electrochemical properties. In
particular, the solvothermally synthesized LiTi2(PO4)3/C
composite exhibits superior high-rate-discharge capability
and cycling stability. A capacity of approximately
$97.7 \%$ of the initial capacity was maintained for the
solvothermal sample after 500 cycles at 5 C.},
cin = {IEK-9},
ddc = {540},
cid = {I:(DE-Juel1)IEK-9-20110218},
pnm = {131 - Electrochemical Storage (POF3-131) / HITEC -
Helmholtz Interdisciplinary Doctoral Training in Energy and
Climate Research (HITEC) (HITEC-20170406)},
pid = {G:(DE-HGF)POF3-131 / G:(DE-Juel1)HITEC-20170406},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000380043500016},
doi = {10.1002/celc.201600125},
url = {https://juser.fz-juelich.de/record/810888},
}