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100 1 _ |a Yu, Shicheng
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245 _ _ |a LiTi$_{2}$(PO$_{4}$)$_{3}$/C Anode Material with a Spindle-Like Morphology for Batteries with High Rate Capability and Improved Cycle Life
260 _ _ |a Weinheim
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|b Wiley-VCH
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520 _ _ |a Nanocrystalline LiTi2(PO4)3/C has been synthesized by employing a solvothermal process in which oxalic acid was used as a solubilizer for the titanium source, a surfactant, and a carbon source. Additionally, Pechini's sol–gel-based method was also used as the synthesis method for comparison. LiTi2(PO4)3/C prepared by using a solvothermal route showed a homogenous particle size with spindle-like microstructures formed from self-assembled nanosized-platelets, whereas preparation by the sol–gel process resulted in agglomerated powders with irregular morphology and particle size. The different morphologies of LiTi2(PO4)3/C prepared in the two synthesis methods tend to form different electrode layer structures, which results in remarkable differences in their electrochemical properties. In particular, the solvothermally synthesized LiTi2(PO4)3/C composite exhibits superior high-rate-discharge capability and cycling stability. A capacity of approximately 97.7 % of the initial capacity was maintained for the solvothermal sample after 500 cycles at 5 C.
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700 1 _ |a Tempel, Hermann
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700 1 _ |a Schierholz, Roland
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700 1 _ |a Aslanbas, Özgür
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700 1 _ |a Mertens, Josef
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700 1 _ |a Gao, Xin
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700 1 _ |a de Haart, L. G. J.
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700 1 _ |a Kungl, Hans
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700 1 _ |a Eichel, Rüdiger-A.
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773 _ _ |a 10.1002/celc.201600125
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