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@ARTICLE{Beridze:811653,
author = {Beridze, George and Birnie, April and Koniski, Sarah and
Ji, Yaqi and Kowalski, Piotr},
title = {{DFT} + {U} as a reliable method for efficient ab initio
calculations of nuclear materials},
journal = {Progress in nuclear energy},
volume = {92},
issn = {0149-1970},
address = {Amsterdam [u.a.]},
publisher = {Elsevier Science},
reportid = {FZJ-2016-04043},
pages = {142 - 146},
year = {2016},
abstract = {Density functional theory (DFT)-based ab initio methods
become standard research tools in various research fields,
including nuclear materials science. However, having
strongly correlated f-electrons, lanthanide- and
actinide-bearing nuclear materials are computationally
challenging for DFT methods and straightforward DFT
calculations of these materials can easily produce false
results. In this contribution we benchmark the DFT + U
method, with the Hubbard U parameter derived ab initio, for
prediction of structural and thermochemical parameters of
nuclear materials, including various actinide-bearing
molecular complexes and lanthanide-bearing monazite- and
xenotime-type prospective ceramic nuclear waste host forms.
Our studies show that the applied DFT + U method improves
significantly prediction of DFT by producing results with
uncertainties similar to those of the higher order, but
computationally unfeasible ab initio methods, and the
experimental data, and thus allows for reliable and feasible
ab initio computation of even chemically complex nuclear
materials.},
cin = {IEK-6 / JARA-HPC},
ddc = {620},
cid = {I:(DE-Juel1)IEK-6-20101013 / $I:(DE-82)080012_20140620$},
pnm = {161 - Nuclear Waste Management (POF3-161) / BMBF-02NUK021A
- Verbundprojekt Conditioning: Grundlegende Untersuchungen
zur Immobilisierung langlebiger Radionuklide mittels Einbau
in endlagerrelevante Keramiken; Teilprojekt A
(BMBF-02NUK021A) / Investigation of the new materials for
safe management of high level nuclear waste.
$(jiek61_20131101)$ / Investigation of the new materials for
safe management of high level nuclear waste.
$(jara0038_20121101)$ / Towards controlled QCD transport
coefficients $(jara0039_20121101)$ / HITEC - Helmholtz
Interdisciplinary Doctoral Training in Energy and Climate
Research (HITEC) (HITEC-20170406)},
pid = {G:(DE-HGF)POF3-161 / G:(DE-Juel1)BMBF-02NUK021A /
$G:(DE-Juel1)jiek61_20131101$ /
$G:(DE-Juel1)jara0038_20121101$ /
$G:(DE-Juel1)jara0039_20121101$ /
G:(DE-Juel1)HITEC-20170406},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000384786400015},
doi = {10.1016/j.pnucene.2016.07.012},
url = {https://juser.fz-juelich.de/record/811653},
}