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000811843 1001_ $$0P:(DE-HGF)0$$aMin, K.-E.$$b0
000811843 245__ $$aA broadband cavity enhanced absorption spectrometer for aircraft measurements of glyoxal, methylglyoxal, nitrous acid, nitrogen dioxide, and water vapor
000811843 260__ $$aKatlenburg-Lindau$$bCopernicus$$c2016
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000811843 520__ $$aWe describe a two-channel broadband cavity enhanced absorption spectrometer (BBCEAS) for aircraft measurements of glyoxal (CHOCHO), methylglyoxal (CH3COCHO), nitrous acid (HONO), nitrogen dioxide (NO2), and water (H2O). The instrument spans 361–389 and 438–468 nm, using two light-emitting diodes (LEDs) and a single grating spectrometer with a charge-coupled device (CCD) detector. Robust performance is achieved using a custom optical mounting system, high-power LEDs with electronic on/off modulation, high-reflectivity cavity mirrors, and materials that minimize analyte surface losses. We have successfully deployed this instrument during two aircraft and two ground-based field campaigns to date. The demonstrated precision (2σ) for retrievals of CHOCHO, HONO and NO2 are 34, 350, and 80 parts per trillion (pptv) in 5 s. The accuracy is 5.8, 9.0, and 5.0 %, limited mainly by the available absorption cross sections.
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000811843 7001_ $$0P:(DE-HGF)0$$aWashenfelder, R. A.$$b1$$eCorresponding author
000811843 7001_ $$0P:(DE-HGF)0$$aDubé, W. P.$$b2
000811843 7001_ $$0P:(DE-HGF)0$$aLangford, A. O.$$b3
000811843 7001_ $$0P:(DE-HGF)0$$aEdwards, P. M.$$b4
000811843 7001_ $$0P:(DE-HGF)0$$aZarzana, K. J.$$b5
000811843 7001_ $$0P:(DE-HGF)0$$aStutz, J.$$b6
000811843 7001_ $$0P:(DE-Juel1)6776$$aLu, Keding$$b7
000811843 7001_ $$0P:(DE-Juel1)16347$$aRohrer, F.$$b8$$ufzj
000811843 7001_ $$0P:(DE-HGF)0$$aZhang, Y.$$b9
000811843 7001_ $$0P:(DE-HGF)0$$aBrown, S. S.$$b10
000811843 773__ $$0PERI:(DE-600)2505596-3$$a10.5194/amt-9-423-2016$$gVol. 9, no. 2, p. 423 - 440$$n2$$p423 - 440$$tAtmospheric measurement techniques$$v9$$x1867-8548$$y2016
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