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@ARTICLE{Schlag:811869,
author = {Schlag, Patrick and Kiendler-Scharr, Astrid and Blom,
Marcus Johannes and Canonaco, Francesco and Henzing, Jeroen
Sebastiaan and Moerman, Marcel and Prévôt, André Stephan
Henry and Holzinger, Rupert},
title = {{A}erosol source apportionment from 1-year measurements at
the {CESAR} tower in {C}abauw, the {N}etherlands},
journal = {Atmospheric chemistry and physics},
volume = {16},
number = {14},
issn = {1680-7324},
address = {Katlenburg-Lindau},
publisher = {EGU},
reportid = {FZJ-2016-04211},
pages = {8831 - 8847},
year = {2016},
abstract = {Intensive measurements of submicron aerosol particles and
their chemical composition were performed with an Aerosol
Chemical Speciation Monitor (ACSM) at the Cabauw
Experimental Site for Atmospheric Research (CESAR) in
Cabauw, the Netherlands, sampling at 5 m height above
ground. The campaign lasted nearly 1 year from July 2012 to
June 2013 as part of the EU-FP7-ACTRIS project (Q-ACSM
Network). Including equivalent black carbon an average
particulate mass concentration of 9.50 µg m−3 was
obtained during the whole campaign with dominant
contributions from ammonium nitrate $(45 \%),$ organic
aerosol (OA, $29 \%),$ and ammonium sulfate $(19 \%).$
There were 12 exceedances of the World Health Organization
(WHO) PM2.5 daily mean limit (25 µg m−3) observed at
this rural site using PM1 instrumentation only. Ammonium
nitrate and OA represented the largest contributors to total
particulate matter during periods of exceedance.Source
apportionment of OA was performed season-wise by positive
matrix factorization (PMF) using the multilinear engine 2
(ME-2) controlled via the source finder (SoFi). Primary
organic aerosols were attributed mainly to traffic
$(8–16 \%$ contribution to total OA, averaged
season-wise) and biomass burning $(0–23 \%).$ Secondary
organic aerosols (SOAs, $61–84 \%)$ dominated the
organic fraction during the whole campaign, particularly on
days with high mass loadings. A SOA factor which is
attributed to humic-like substances (HULIS) was identified
as a highly oxidized background aerosol in Cabauw. This
shows the importance of atmospheric aging processes for
aerosol concentration at this rural site. Due to the large
secondary fraction, the reduction of particulate mass at
this rural site is challenging on a local scale.},
cin = {IEK-8},
ddc = {550},
cid = {I:(DE-Juel1)IEK-8-20101013},
pnm = {243 - Tropospheric trace substances and their
transformation processes (POF3-243) / ACTRIS - Aerosols,
Clouds, and Trace gases Research Infrastructure Network
(262254)},
pid = {G:(DE-HGF)POF3-243 / G:(EU-Grant)262254},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000381213300007},
doi = {10.5194/acp-16-8831-2016},
url = {https://juser.fz-juelich.de/record/811869},
}