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@ARTICLE{Rosca:814,
      author       = {Rosca, V. and Beltramo, G. L. and Koper, M. T. M.},
      title        = {{R}eduction of {NO} adlayers on {P}t(110) and {P}t(111) in
                      acidic media: {E}vidence for adsorption site-specific
                      reduction},
      journal      = {Langmuir},
      volume       = {21},
      issn         = {0743-7463},
      address      = {Washington, DC},
      publisher    = {ACS Publ.},
      reportid     = {PreJuSER-814},
      pages        = {1448 - 1456},
      year         = {2005},
      note         = {Record converted from VDB: 12.11.2012},
      abstract     = {We present a combined in situ Fourier transform infrared
                      reflection-absorption spectroscopy and voltammetric study of
                      the reduction of saturated and subsaturated NO adlayers on
                      Pt(111) and Pt(110) single-crystal surfaces in acidic media.
                      The stripping voltammetry experiments and the associated
                      evolution of infrared spectra indicate that different
                      features (peaks) observed in the voltammetric profile for
                      the electrochemical reduction of NO adlayers on the surfaces
                      considered are related to the reduction of NO(ads) at
                      different adsorption sites and not to different
                      (consecutive) processes. More specifically, reduction of
                      high- and intermediate-coverage (ca. 0.5-1 monolayers (ML))
                      NO adlayers on Pt(110) is accompanied by site switching from
                      atop to bridge position, in agreement with the
                      ultra-high-vacuum data. On Pt(111) linearly bonded (atop) NO
                      and face-centered cubic 3-fold-hollow NO species coexist at
                      high coverages (0.25-0.5 ML) and can be reduced
                      consecutively and independently. On Pt(111) and Pt(110)
                      electrodes, linearly bonded NO species are more reactive
                      than multifold-bonded NO species. Both spectroscopic and
                      voltammetric data indicate that ammonia is the main product
                      of NO(ads) reduction on the two surfaces examined.},
      keywords     = {J (WoSType)},
      cin          = {ISG-4},
      ddc          = {670},
      cid          = {I:(DE-Juel1)VDB421},
      pnm          = {Kondensierte Materie},
      pid          = {G:(DE-Juel1)FUEK242},
      shelfmark    = {Chemistry, Multidisciplinary / Chemistry, Physical /
                      Materials Science, Multidisciplinary},
      typ          = {PUB:(DE-HGF)16},
      pubmed       = {pmid:15697294},
      UT           = {WOS:000226962100046},
      doi          = {10.1021/la0475831},
      url          = {https://juser.fz-juelich.de/record/814},
}