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@ARTICLE{Lazic:8160,
author = {Lazic, P. and Alaei, M. and Atodiresei, N. and Caciuc, V.
and Brako, R. and Blügel, S.},
title = {{D}ensity functional theory with nonlocal correlation: {A}
key to the solution of the {CO} adsorption puzzle},
journal = {Physical review / B},
volume = {81},
number = {4},
issn = {1098-0121},
address = {College Park, Md.},
publisher = {APS},
reportid = {PreJuSER-8160},
pages = {045401},
year = {2010},
note = {The calculations were performed on the JUMP and Blue/Gene
supercomputers at the Forschungszentrum Julich,Germany. Two
of us, P. L. and S. B., thank the Deutsche
Forschungsgemeinschaft (DFG) (Priority Programme "Molecular
Magnetism") and Alexander von Humboldt foundation for
financial support. N. A. acknowledges the support of Japan
Society for the Promotion of Science. R. B. acknowledges the
support of MSES of the Republic of Croatia through Project
No. 098-0352828-2836EPS.},
abstract = {We study the chemisorption of CO molecule into sites of
different coordination on (111) surfaces of late 4d and 5d
transition metals. In an attempt to solve the well-known CO
adsorption puzzle, i.e., discrepancies of adsorption site
preferences with experiment which appear in the standard
density functional theory calculations, we have applied the
relatively new van der Waals-density functional of nonlocal
correlation. In all considered cases this reduces or
completely solves the site preference discrepancies and
improves the value of the adsorption energy. By introducing
a cutoff distance for nonlocal interaction we can pinpoint
the length scale at which the correlation plays a major role
in the systems considered.},
keywords = {J (WoSType)},
cin = {IAS-1 / IFF-1 / JARA-FIT / JARA-HPC},
ddc = {530},
cid = {I:(DE-Juel1)IAS-1-20090406 / I:(DE-Juel1)VDB781 /
$I:(DE-82)080009_20140620$ / I:(DE-Juel1)VDB1346},
pnm = {Grundlagen für zukünftige Informationstechnologien},
pid = {G:(DE-Juel1)FUEK412},
shelfmark = {Physics, Condensed Matter},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000274002500083},
doi = {10.1103/PhysRevB.81.045401},
url = {https://juser.fz-juelich.de/record/8160},
}