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@ARTICLE{Blum:817737,
author = {Blum, Ludger},
title = {{A}n {A}nalysis of {C}ontact {P}roblems in {S}olid {O}xide
{F}uel {C}ell {S}tacks {A}rising from {D}ifferences in
{T}hermal {E}xpansion {C}oefficients},
journal = {Electrochimica acta},
volume = {223},
issn = {0013-4686},
address = {New York, NY [u.a.]},
publisher = {Elsevier},
reportid = {FZJ-2016-04380},
pages = {100 - 108},
year = {2017},
abstract = {The successful operation of solid oxide fuel cells (SOFC)
imposes high demands on the similarity of the thermal
expansion coefficients of the materials used. This is not
only due to thermo-mechanical factors but also because of
the risk of contact loss via the formation of a micro-gap
between the electrodes and adjacent contact layers caused by
temperature changes. The origin of the formation of such a
gap between the different layers in an SOFC stack is
investigated on the basis of various material combinations.
A comparison with successful and failed stack test results
reveals that there is a high probability of contact problems
if the calculated gap on the cathode side exceeds 200 nm.
This limit relates to the maximum possible elastic
deformation of the combination of the cathode and cathode
contact layer (CCL). Such contact problems can be avoided in
the current design by utilizing an appropriate combination
of the cathode, CCL and glass-ceramic material that can be
selected on the basis of the methodology outlined in the
current work. This optimization in materials selection will
help to establish a stack technology that allows high power
density with a minimized risk of failure of single layers.},
cin = {IEK-3},
ddc = {540},
cid = {I:(DE-Juel1)IEK-3-20101013},
pnm = {135 - Fuel Cells (POF3-135) / SOFC - Solid Oxide Fuel Cell
(SOFC-20140602)},
pid = {G:(DE-HGF)POF3-135 / G:(DE-Juel1)SOFC-20140602},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000392773100011},
doi = {10.1016/j.electacta.2016.12.016},
url = {https://juser.fz-juelich.de/record/817737},
}