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000817864 1001_ $$0P:(DE-HGF)0$$aKao, Y. J.$$b0
000817864 245__ $$aHydroxyl defect effect on the resistance degradation behavior in Y-doped (Ba,Ca)(Ti,Zr)O$_{3}$ bulk ceramics
000817864 260__ $$aAmsterdam [u.a.]$$bElsevier Science$$c2016
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000817864 520__ $$aDegradation behavior of acceptor (Y)-doped (Ba,Ca)(Ti,Zr)O3 ceramics sintered in moist reducing atmosphere and subsequently re-oxidized in dry or wet atmospheres was contrasted. The degradation behavior critically depends on the water vapor incorporation, the time to degradation systematically decreased with the incorporation of hydroxyl defects View the MathML source(OH)O•. The electrical conductivity was investigated by means of impedance spectroscopy (IS) to determine properties, such as grain and grain boundary conductivity, grain boundary potential barrier height, and space charge layer thickness. Furthermore, transmission electron microscopy (TEM) and electron energy loss spectroscopy (EELS) were applied to consider microstructure, microchemistry, and oxygen stoichiometry changes.
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000817864 7001_ $$0P:(DE-HGF)0$$aHuang, C. Y.$$b1$$eCorresponding author
000817864 7001_ $$0P:(DE-HGF)0$$aSu, C. Y.$$b2
000817864 7001_ $$0P:(DE-Juel1)130894$$aPithan, C.$$b3$$ufzj
000817864 7001_ $$0P:(DE-HGF)0$$aHennings, D. F.$$b4
000817864 7001_ $$0P:(DE-Juel1)131022$$aWaser, R.$$b5$$ufzj
000817864 773__ $$0PERI:(DE-600)2013983-4$$a10.1016/j.jeurceramsoc.2016.04.041$$gVol. 36, no. 13, p. 3147 - 3155$$n13$$p3147 - 3155$$tJournal of the European Ceramic Society$$v36$$x0955-2219$$y2016
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