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@ARTICLE{Kao:817864,
      author       = {Kao, Y. J. and Huang, C. Y. and Su, C. Y. and Pithan, C.
                      and Hennings, D. F. and Waser, R.},
      title        = {{H}ydroxyl defect effect on the resistance degradation
                      behavior in {Y}-doped ({B}a,{C}a)({T}i,{Z}r){O}$_{3}$ bulk
                      ceramics},
      journal      = {Journal of the European Ceramic Society},
      volume       = {36},
      number       = {13},
      issn         = {0955-2219},
      address      = {Amsterdam [u.a.]},
      publisher    = {Elsevier Science},
      reportid     = {FZJ-2016-04472},
      pages        = {3147 - 3155},
      year         = {2016},
      abstract     = {Degradation behavior of acceptor (Y)-doped (Ba,Ca)(Ti,Zr)O3
                      ceramics sintered in moist reducing atmosphere and
                      subsequently re-oxidized in dry or wet atmospheres was
                      contrasted. The degradation behavior critically depends on
                      the water vapor incorporation, the time to degradation
                      systematically decreased with the incorporation of hydroxyl
                      defects View the MathML source(OH)O•. The electrical
                      conductivity was investigated by means of impedance
                      spectroscopy (IS) to determine properties, such as grain and
                      grain boundary conductivity, grain boundary potential
                      barrier height, and space charge layer thickness.
                      Furthermore, transmission electron microscopy (TEM) and
                      electron energy loss spectroscopy (EELS) were applied to
                      consider microstructure, microchemistry, and oxygen
                      stoichiometry changes.},
      cin          = {PGI-7},
      ddc          = {660},
      cid          = {I:(DE-Juel1)PGI-7-20110106},
      pnm          = {524 - Controlling Collective States (POF3-524)},
      pid          = {G:(DE-HGF)POF3-524},
      typ          = {PUB:(DE-HGF)16},
      UT           = {WOS:000378449100008},
      doi          = {10.1016/j.jeurceramsoc.2016.04.041},
      url          = {https://juser.fz-juelich.de/record/817864},
}