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@ARTICLE{Doppler:817904,
      author       = {Doppler, M. C. and Fleig, J. and Bram, M. and Opitz, A. K.},
      title        = {{T}he {C}apacitance of {N}ickel {P}attern {E}lectrodes on
                      {Z}irconia {E}lectrolyte},
      journal      = {Journal of the Electrochemical Society},
      volume       = {163},
      number       = {10},
      issn         = {1945-7111},
      address      = {Pennington, NJ},
      publisher    = {Electrochemical Soc.},
      reportid     = {FZJ-2016-04502},
      pages        = {H1019 - H1025},
      year         = {2016},
      abstract     = {Micro-structured thin-film electrodes were employed to
                      investigate the capacitive behavior of nickel on
                      yttria-stabilized zirconia (YSZ) electrolytes by means of
                      electrochemical impedance spectroscopy. Electrodes with
                      different shapes and electrode areas clearly showed a linear
                      relationship between capacitance and the electrode area.
                      Electrostatic double layer models, however, could not
                      explain the observed area specific capacitance value of ca.
                      3 F/m². This fact, the characteristic voltage dependence
                      with a hysteresis, and the effect of H2S on the electrode
                      capacitance indicate substantial contributions of a chemical
                      capacitance. Possible types of chemical capacitance in the
                      system Ni(H2/H2O)/YSZ are discussed and an oxygen partial
                      pressure dependent mechanism change is suggested.},
      cin          = {IEK-1},
      ddc          = {540},
      cid          = {I:(DE-Juel1)IEK-1-20101013},
      pnm          = {135 - Fuel Cells (POF3-135) / SOFC - Solid Oxide Fuel Cell
                      (SOFC-20140602)},
      pid          = {G:(DE-HGF)POF3-135 / G:(DE-Juel1)SOFC-20140602},
      typ          = {PUB:(DE-HGF)16},
      UT           = {WOS:000389150900121},
      doi          = {10.1149/2.0951610jes},
      url          = {https://juser.fz-juelich.de/record/817904},
}