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| Hauptseite > Publikationsdatenbank > The Capacitance of Nickel Pattern Electrodes on Zirconia Electrolyte > print |
| Hauptseite > Publikationsdatenbank > The Capacitance of Nickel Pattern Electrodes on Zirconia Electrolyte > print |
| 001 | 817904 | ||
| 005 | 20240711085622.0 | ||
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| 245 | _ | _ | |a The Capacitance of Nickel Pattern Electrodes on Zirconia Electrolyte |
| 260 | _ | _ | |a Pennington, NJ |c 2016 |b Electrochemical Soc. |
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| 520 | _ | _ | |a Micro-structured thin-film electrodes were employed to investigate the capacitive behavior of nickel on yttria-stabilized zirconia (YSZ) electrolytes by means of electrochemical impedance spectroscopy. Electrodes with different shapes and electrode areas clearly showed a linear relationship between capacitance and the electrode area. Electrostatic double layer models, however, could not explain the observed area specific capacitance value of ca. 3 F/m². This fact, the characteristic voltage dependence with a hysteresis, and the effect of H2S on the electrode capacitance indicate substantial contributions of a chemical capacitance. Possible types of chemical capacitance in the system Ni(H2/H2O)/YSZ are discussed and an oxygen partial pressure dependent mechanism change is suggested. |
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| 773 | _ | _ | |a 10.1149/2.0951610jes |g Vol. 163, no. 10, p. H1019 - H1025 |0 PERI:(DE-600)2002179-3 |n 10 |p H1019 - H1025 |t Journal of the Electrochemical Society |v 163 |y 2016 |x 1945-7111 |
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