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000817927 1001_ $$0P:(DE-HGF)0$$aMurphy, Gabriel L.$$b0
000817927 245__ $$aNonstoichiometry in Strontium Uranium Oxide: Understanding the Rhombohedral–Orthorhombic Transition in SrUO$_{4}$
000817927 260__ $$aWashington, DC$$bAmerican Chemical Society$$c2016
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000817927 520__ $$aIn situ neutron and synchrotron X-ray diffraction studies demonstrate that SrUO4 acts as an oxygen transfer agent, forming oxygen vacancies under both oxidizing and reducing conditions. Two polymorphs of SrUO4 are stable at room temperature, and the transformation between these is observed to be associated with thermally regulated diffusion of oxygen ions, with partial reduction of the U6+ playing a role in both the formation of oxygen deficient α-SrUO4−δ and its subsequent transformation to stoichiometric β-SrUO4. This is supported by ab initio calculations using density functional theory calculations. The oxygen vacancies play a critical role in the first order transition that SrUO4 undergoes near 830 °C. The changes in the oxidation states and U geometry associated with the structural phase transition have been characterized using X-ray absorption spectroscopy, synchrotron X-ray diffraction, and neutron diffraction.
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000817927 536__ $$0G:(DE-Juel1)jara0039_20121101$$aTowards controlled QCD transport coefficients (jara0039_20121101)$$cjara0039_20121101$$fTowards controlled QCD transport coefficients$$x3
000817927 536__ $$0G:(DE-Juel1)HITEC-20170406$$aHITEC - Helmholtz Interdisciplinary Doctoral Training in Energy and Climate Research (HITEC) (HITEC-20170406)$$cHITEC-20170406$$x4
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000817927 7001_ $$0P:(DE-HGF)0$$aKennedy, Brendan J.$$b1$$eCorresponding author
000817927 7001_ $$0P:(DE-HGF)0$$aKimpton, Justin A.$$b2
000817927 7001_ $$0P:(DE-HGF)0$$aGu, Qinfen$$b3
000817927 7001_ $$0P:(DE-HGF)0$$aJohannessen, Bernt$$b4
000817927 7001_ $$0P:(DE-Juel1)156345$$aBeridze, George$$b5$$ufzj
000817927 7001_ $$0P:(DE-Juel1)137024$$aKowalski, Piotr$$b6
000817927 7001_ $$0P:(DE-Juel1)130324$$aBosbach, Dirk$$b7$$ufzj
000817927 7001_ $$0P:(DE-HGF)0$$aAvdeev, Maxim$$b8
000817927 7001_ $$0P:(DE-HGF)0$$aZhang, Zhaoming$$b9
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