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000818245 1001_ $$0P:(DE-Juel1)156589$$aSchwarz, Daniel$$b0
000818245 245__ $$aTowards functionalization of graphene: in situ study of the nucleation of copper-phtalocyanine on graphene
000818245 260__ $$a[Bad Honnef]$$bDt. Physikalische Ges.$$c2016
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000818245 520__ $$aMolecular films present an elegant way for the uniform functionalization or doping of graphene. Here, we present an in situ study on the initial growth of copper phthalocyanine (CuPc) on epitaxial graphene on Ir(111). We followed the growth up to a closed monolayer with low energy electron microscopy and selected area electron diffraction (μLEED). The molecules coexist on graphene in a disordered phase without long-range order and an ordered crystalline phase. The local topography of the graphene substrate plays an important role in the nucleation process of the crystalline phase. Graphene flakes on Ir(111) feature regions that are under more tensile stress than others. We observe that the CuPc molecules form ordered domains initially on those graphene regions that are closest to the fully relaxed lattice. We attribute this effect to a stronger influence of the underlying Ir(111) substrate for molecules adsorbed on those relaxed regions.
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000818245 7001_ $$0P:(DE-Juel1)145773$$aHenneke, Caroline$$b1$$ufzj
000818245 7001_ $$0P:(DE-Juel1)128774$$aKumpf, Christian$$b2$$eCorresponding author$$ufzj
000818245 773__ $$0PERI:(DE-600)1464444-7$$a10.1088/1367-2630/18/2/023034$$gVol. 18, no. 2, p. 023034 -$$n2$$p023034$$tNew journal of physics$$v18$$x1367-2630$$y2016
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