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@ARTICLE{Papagiannopoulos:819433,
      author       = {Papagiannopoulos, Aristeidis and Sotiropoulos, Konstantinos
                      and Radulescu, Aurel},
      title        = {{S}cattering investigation of multiscale organization in
                      aqueous solutions of native xanthan},
      journal      = {Carbohydrate polymers},
      volume       = {153},
      issn         = {0144-8617},
      address      = {Amsterdam [u.a.]},
      publisher    = {Elsevier Science},
      reportid     = {FZJ-2016-05097},
      pages        = {196 - 202},
      year         = {2016},
      abstract     = {The hierarchical morphology of xanthan solutions is
                      analyzed by light and neutron scattering in a broad range of
                      concentrations in order to connect their morphology to their
                      well-documented dynamic properties. Static light scattering
                      inside the semidilute regime is dominated by the form factor
                      of individual xanthan chains while at higher concentrations
                      chain interconnections appear to modify the low wave vector
                      scattering. Dynamic light scattering reveals the
                      self-similar nature of the solutions caused by interchain
                      associations as intensity autocorrelation functions present
                      power-law behaviour. Small angle neutron scattering is
                      dominated by the fractal scattering from the formed network
                      at intermediate length scales. At small length scales the
                      rigid structure of xanthan is revealed and the molecular
                      weight per unit length is extracted. No detectable
                      morphological alterations for shear rates up to 1000 rad/s
                      are observed revealing that the shear thinning behaviour of
                      xanthan is related to the disruption of chain-chain
                      associations.},
      cin          = {JCNS (München) ; Jülich Centre for Neutron Science JCNS
                      (München) ; JCNS-FRM-II / Neutronenstreuung ; JCNS-1},
      ddc          = {540},
      cid          = {I:(DE-Juel1)JCNS-FRM-II-20110218 /
                      I:(DE-Juel1)JCNS-1-20110106},
      pnm          = {6G4 - Jülich Centre for Neutron Research (JCNS) (POF3-623)
                      / 6G15 - FRM II / MLZ (POF3-6G15)},
      pid          = {G:(DE-HGF)POF3-6G4 / G:(DE-HGF)POF3-6G15},
      experiment   = {EXP:(DE-588)4443767-5 / EXP:(DE-MLZ)KWS2-20140101},
      typ          = {PUB:(DE-HGF)16},
      UT           = {WOS:000382317200023},
      doi          = {10.1016/j.carbpol.2016.07.104},
      url          = {https://juser.fz-juelich.de/record/819433},
}