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@ARTICLE{Abramov:819520,
      author       = {Abramov, Pavel A. and Peresypkina, Eugenia V. and Izarova,
                      Natalya and Vicent, Cristian and Zhdanov, Artem A. and
                      Kompankov, Nikolay B. and Gutsul, Tatiana and Sokolov, Maxim
                      N.},
      title        = {{P}olyoxoanions assembled by the condensation of vanadate,
                      tungstate and selenite: solution studies and crystal
                      structures of the mixed metal derivatives ({NM}e $_{4}$)
                      $_{2}$ {N}a $_{2}$ [{W}$^{{VI}}$ $_{4}$ {V} $^{{V}}$ $_{2}$
                      {O} $_{19}$ ]·8{H}$_{2}${O} and ({NM}e$_{4}$ )$_{4.83}$
                      [({S}e$^{{IV}}${W}$^{{VI}}$$_{4.57}$
                      {V}$^{{V}}$$_{4.43}${O}$_{33}$)$_{2}$
                      ({W}$^{{VI}}$({O})({H}$_{2}${O}))({V} $^{{V}}${O}) $_{2.6}$
                      ]·10.57{H}$_{2}${O}},
      journal      = {New journal of chemistry},
      volume       = {40},
      number       = {2},
      issn         = {0398-9836},
      address      = {London},
      publisher    = {RSC},
      reportid     = {FZJ-2016-05163},
      pages        = {937 - 944},
      year         = {2016},
      abstract     = {The reaction of acidified aqueous solutions of Na2WO4,
                      NaVO3 and SeO2 in a 16 : 4 : 3 molar ratio gives a
                      complex mixture of polyoxometalates (POMs) with both WVI and
                      VV addenda, formulated as
                      [(SeIVWVIxVV9−xO33)2(WVIO(H2O))(VO)m]n− with x = 4, 5,
                      6; m = 2 or 3. In solution, the sandwich-type complexes
                      [(SeIVWVIxVV9−xO33)2(WVIO(H2O))(VO)m]n− slowly lose Se
                      and convert into [WVI4VV2O19]4− and further to
                      [WVI5VVO19]3− with a Lindqvist-type structure. These
                      transformations were monitored with 51V and 77Se NMR,
                      electrospray mass-spectrometry and capillary
                      electrophoresis. Crystals of (NMe4)2Na2[(W4V2)O19]·8H2O (1)
                      and
                      (NMe4)4.83[(SeW4.57V4.43O33)2(W(O)(H2O))(VO)2.6]·10.57H2O
                      (2) were isolated and structurally characterized.},
      cin          = {PGI-6},
      ddc          = {540},
      cid          = {I:(DE-Juel1)PGI-6-20110106},
      pnm          = {522 - Controlling Spin-Based Phenomena (POF3-522)},
      pid          = {G:(DE-HGF)POF3-522},
      typ          = {PUB:(DE-HGF)16},
      UT           = {WOS:000371559000010},
      doi          = {10.1039/C5NJ00858A},
      url          = {https://juser.fz-juelich.de/record/819520},
}