Hauptseite > Publikationsdatenbank > Polyoxoanions assembled by the condensation of vanadate, tungstate and selenite: solution studies and crystal structures of the mixed metal derivatives (NMe $_{4}$) $_{2}$ Na $_{2}$ [W$^{VI}$ $_{4}$ V $^{V}$ $_{2}$ O $_{19}$ ]·8H$_{2}$O and (NMe$_{4}$ )$_{4.83}$ [(Se$^{IV}$W$^{VI}$$_{4.57}$ V$^{V}$$_{4.43}$O$_{33}$)$_{2}$ (W$^{VI}$(O)(H$_{2}$O))(V $^{V}$O) $_{2.6}$ ]·10.57H$_{2}$O > print

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024 7 _ |a 10.1039/C5NJ00858A
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024 7 _ |a 0398-9836
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082 _ _ |a 540
100 1 _ |a Abramov, Pavel A.
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245 _ _ |a Polyoxoanions assembled by the condensation of vanadate, tungstate and selenite: solution studies and crystal structures of the mixed metal derivatives (NMe $_{4}$) $_{2}$ Na $_{2}$ [W$^{VI}$ $_{4}$ V $^{V}$ $_{2}$ O $_{19}$ ]·8H$_{2}$O and (NMe$_{4}$ )$_{4.83}$ [(Se$^{IV}$W$^{VI}$$_{4.57}$ V$^{V}$$_{4.43}$O$_{33}$)$_{2}$ (W$^{VI}$(O)(H$_{2}$O))(V $^{V}$O) $_{2.6}$ ]·10.57H$_{2}$O
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520 _ _ |a The reaction of acidified aqueous solutions of Na2WO4, NaVO3 and SeO2 in a 16 : 4 : 3 molar ratio gives a complex mixture of polyoxometalates (POMs) with both WVI and VV addenda, formulated as [(SeIVWVIxVV9−xO33)2(WVIO(H2O))(VO)m]n− with x = 4, 5, 6; m = 2 or 3. In solution, the sandwich-type complexes [(SeIVWVIxVV9−xO33)2(WVIO(H2O))(VO)m]n− slowly lose Se and convert into [WVI4VV2O19]4− and further to [WVI5VVO19]3− with a Lindqvist-type structure. These transformations were monitored with 51V and 77Se NMR, electrospray mass-spectrometry and capillary electrophoresis. Crystals of (NMe4)2Na2[(W4V2)O19]·8H2O (1) and (NMe4)4.83[(SeW4.57V4.43O33)2(W(O)(H2O))(VO)2.6]·10.57H2O (2) were isolated and structurally characterized.
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700 1 _ |a Peresypkina, Eugenia V.
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700 1 _ |a Izarova, Natalya
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700 1 _ |a Vicent, Cristian
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700 1 _ |a Zhdanov, Artem A.
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700 1 _ |a Kompankov, Nikolay B.
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700 1 _ |a Gutsul, Tatiana
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700 1 _ |a Sokolov, Maxim N.
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773 _ _ |a 10.1039/C5NJ00858A
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