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@ARTICLE{Valov:819524,
author = {Valov, Ilia and Lu, Wei D.},
title = {{N}anoscale electrochemistry using dielectric thin films as
solid electrolytes},
journal = {Nanoscale},
volume = {8},
number = {29},
issn = {2040-3372},
address = {Cambridge},
publisher = {RSC Publ.},
reportid = {FZJ-2016-05167},
pages = {13828 - 13837},
year = {2016},
abstract = {It is now well known that at the nanoscale matters behave
differently compared to bulk phases. Increased reactivity,
deviations in structural, thermodynamic and kinetic
properties make nanoscale materials and processes attractive
for both fundamental research and applications. Here we show
that nanometer thin films of materials with dielectric
properties at the macroscopic level such as SiO2, Ta2O5 and
HfO2 behave as solid electrolytes and exhibit evident ionic
transport and electrochemical redox reactions. Experimental
studies demonstrate that classical electrochemical
potentiodynamic and steady state methods can be used to
study the mass and charge transport at the nanoscale. We
believe these reported properties of nanomatter open new
opportunities for fundamental research and applications.},
cin = {PGI-7},
ddc = {600},
cid = {I:(DE-Juel1)PGI-7-20110106},
pnm = {521 - Controlling Electron Charge-Based Phenomena
(POF3-521)},
pid = {G:(DE-HGF)POF3-521},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000381815000002},
pubmed = {pmid:27150952},
doi = {10.1039/C6NR01383J},
url = {https://juser.fz-juelich.de/record/819524},
}