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@ARTICLE{Lang:819526,
      author       = {Lang, Christian and Kohlbrecher, Joachim and Porcar, Lionel
                      and Lettinga, M.P.},
      title        = {{T}he {C}onnection between {B}iaxial {O}rientation and
                      {S}hear {T}hinning for {Q}uasi-{I}deal {R}ods},
      journal      = {Polymers},
      volume       = {8},
      number       = {8},
      issn         = {2073-4360},
      address      = {Basel},
      publisher    = {MDPI},
      reportid     = {FZJ-2016-05169},
      pages        = {291},
      year         = {2016},
      abstract     = {The complete orientational ordering tensor of quasi-ideal
                      colloidal rods is obtainedas a function of shear rate by
                      performing rheo-SANS (rheology with small angle
                      neutronscattering) measurements on isotropic fd-virus
                      suspensions in the two relevant scatteringplanes, the
                      flow-gradient (1-2) and the flow-vorticity (1-3) plane.
                      Microscopic ordering canbe identified as the origin of the
                      observed shear thinning. A qualitative description of
                      therheological response by Smoluchowski, as well as
                      Doi–Edwards–Kuzuu theory is possible,as we obtain a
                      master curve for different concentrations, scaling the shear
                      rate with theapparent collective rotational diffusion
                      coefficient. However, the observation suggests that
                      theinterdependence of ordering and shear thinning at small
                      shear rates is stronger than predicted.The extracted
                      zero-shear viscosity matches the concentration dependence of
                      the self-diffusion ofrods in semi-dilute solutions, while
                      the director tilts close towards the flow direction already
                      atvery low shear rates. In contrast, we observe a smaller
                      dependence on the shear rate in the overallordering at high
                      shear rates, as well as an ever-increasing biaxiality.},
      cin          = {ICS-3},
      ddc          = {540},
      cid          = {I:(DE-Juel1)ICS-3-20110106},
      pnm          = {551 - Functional Macromolecules and Complexes (POF3-551) /
                      DiStruc - Directed Colloidal Structure at the Meso-Scale
                      (641839)},
      pid          = {G:(DE-HGF)POF3-551 / G:(EU-Grant)641839},
      typ          = {PUB:(DE-HGF)16},
      UT           = {WOS:000384520900007},
      doi          = {10.3390/polym8080291},
      url          = {https://juser.fz-juelich.de/record/819526},
}