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@ARTICLE{Kowalski:819818,
author = {Kowalski, Piotr and Ji, Yaqi and Li, Yan and Arinicheva,
Yulia and Beridze, George and Neumeier, Stefan and
Bukaemskiy, Andrey and Bosbach, Dirk},
title = {{S}imulation of ceramic materials relevant for nuclear
waste management: {C}ase of
{L}a$_{1−x}${E}u$_{x}${PO}$_{4}$ solid solution},
journal = {Nuclear instruments $\&$ methods in physics research / B},
volume = {393},
issn = {0168-583X},
address = {Amsterdam [u.a.]},
publisher = {Elsevier},
reportid = {FZJ-2016-05405},
pages = {68–72},
year = {2017},
abstract = {Using powerful computational resources and state-of-the-art
methods of computational chemistry we contribute to the
research on novel nuclear waste forms by providing atomic
scale description of processes that govern the structural
incorporation and the interactions of radionuclides in host
materials. Here we present various results of combined
computational and experimental studies on La1−xEuxPO4
monazite-type solid solution. We discuss the performance of
DFT + U method with the Hubbard U parameter value derived ab
initio, and the derivation of various structural,
thermodynamic and radiation-damage related properties. We
show a correlation between the cation displacement
probabilities and the solubility data, indicating that the
binding of cations is the driving factor behind both
processes. The combined atomistic modeling and experimental
studies result in a superior characterization of the
investigated material.},
cin = {IEK-6 / JARA-HPC},
ddc = {530},
cid = {I:(DE-Juel1)IEK-6-20101013 / $I:(DE-82)080012_20140620$},
pnm = {161 - Nuclear Waste Management (POF3-161) / Investigation
of the new materials for safe management of high level
nuclear waste. $(jiek61_20131101)$ / Investigation of the
new materials for safe management of high level nuclear
waste. $(jara0038_20121101)$ / Towards controlled QCD
transport coefficients $(jara0039_20121101)$ / HITEC -
Helmholtz Interdisciplinary Doctoral Training in Energy and
Climate Research (HITEC) (HITEC-20170406)},
pid = {G:(DE-HGF)POF3-161 / $G:(DE-Juel1)jiek61_20131101$ /
$G:(DE-Juel1)jara0038_20121101$ /
$G:(DE-Juel1)jara0039_20121101$ /
G:(DE-Juel1)HITEC-20170406},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000394194500016},
doi = {10.1016/j.nimb.2016.09.029},
url = {https://juser.fz-juelich.de/record/819818},
}