000819943 001__ 819943
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000819943 1001_ $$0P:(DE-Juel1)157748$$aAlexeev, Pavel$$b0$$eCorresponding author$$ufzj
000819943 1112_ $$a612. Wilhelm und Else Heraeus-Seminar on  "Electrons and phonons: Interfaces and interactions"$$cBad Honnef$$d2016-04-03 - 2016-04-06$$wGermany
000819943 245__ $$aHigh-pressure studies on filled and unfilled skutterudites
000819943 260__ $$c2016
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000819943 520__ $$aSkutterudites are an interesting class of host-guest structure thermoelectric materials. It is possible to tune the transport properties of skutterudites in a wide range by modification of structure and doping. The presence of the large cavities in the structure and the recently proposed self-insertion mechanism make investigations of the high-pressure behavior of skutterudites very interesting. We present compressibility studies on the unfilled CoSb$_3$ and FeSb$_3$ skutterudites, as well on the filled Tl$_0.8$FeCo$_3$Sb$_12$ skutterudite. The studies were carried out by high-pressure synchrotron radiation diffraction. A third order Birch-Murnaghan isothermal equation of state was fitted to the experimental data between ambient pressure and 34 GPa for CoSb$_3$, 14 GPa for FeSb$_3$, and up to 31.4 GPa for Tl$_0.8$FeCo$_3$Sb$_12$.
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000819943 7001_ $$0P:(DE-HGF)0$$aGlazyrin, K.$$b1
000819943 7001_ $$0P:(DE-HGF)0$$aSergueev, I.$$b2
000819943 7001_ $$0P:(DE-HGF)0$$aBednarcik, J.$$b3
000819943 7001_ $$0P:(DE-Juel1)130706$$aHermann, Raphael$$b4$$ufzj
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