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@ARTICLE{Zheng:819971,
      author       = {Zheng, Haiyan and Li, Kuo and Cody, George D. and Tulk,
                      Christopher A. and Dong, Xiao and Gao, Guoying and Molaison,
                      Jamie J. and Liu, Zhenxian and Feygenson, Mikhail and Yang,
                      Wenge and Ivanov, Ilia N. and Basile, Leonardo and Idrobo,
                      Juan-Carlos and Guthrie, Malcolm and Mao, Ho-kwang},
      title        = {{P}olymerization of {A}cetonitrile via a {H}ydrogen
                      {T}ransfer {R}eaction from {CH} 3 to {CN} under {E}xtreme
                      {C}onditions},
      journal      = {Angewandte Chemie / International edition},
      volume       = {55},
      number       = {39},
      issn         = {1433-7851},
      address      = {Weinheim},
      publisher    = {Wiley-VCH},
      reportid     = {FZJ-2016-05538},
      pages        = {12040 - 12044},
      year         = {2016},
      abstract     = {Acetonitrile (CH$_{3}$CN) is the simplest and one of the
                      most stable nitriles. Reactions usually occur on the C≡N
                      triple bond, while the C−H bond is very inert and can only
                      be activated by a very strong base or a metal catalyst. It
                      is demonstrated that C−H bonds can be activated by the
                      cyano group under high pressure, but at room temperature.
                      The hydrogen atom transfers from the CH3 to CN along the
                      CH⋅⋅⋅N hydrogen bond, which produces an amino group
                      and initiates polymerization to form a dimer, 1D chain, and
                      2D nanoribbon with mixed sp2 and sp3 bonded carbon. Finally,
                      it transforms into a graphitic polymer by eliminating
                      ammonia. This study shows that applying pressure can induce
                      a distinctive reaction which is guided by the structure of
                      the molecular crystal. It highlights the fact that very
                      inert C−H can be activated by high pressure, even at room
                      temperature and without a catalyst.},
      cin          = {ICS-1 / Neutronenstreuung ; JCNS-1},
      ddc          = {540},
      cid          = {I:(DE-Juel1)ICS-1-20110106 / I:(DE-Juel1)JCNS-1-20110106},
      pnm          = {551 - Functional Macromolecules and Complexes (POF3-551) /
                      6G4 - Jülich Centre for Neutron Research (JCNS) (POF3-623)
                      / 6215 - Soft Matter, Health and Life Sciences (POF3-621)},
      pid          = {G:(DE-HGF)POF3-551 / G:(DE-HGF)POF3-6G4 /
                      G:(DE-HGF)POF3-6215},
      typ          = {PUB:(DE-HGF)16},
      UT           = {WOS:000384713100062},
      pubmed       = {pmid:27561179},
      doi          = {10.1002/anie.201606198},
      url          = {https://juser.fz-juelich.de/record/819971},
}