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| 001 | 820373 | ||
| 005 | 20240712113013.0 | ||
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| 100 | 1 | _ | |a Hodnik, Nejc |0 0000-0002-7113-9769 |b 0 |e Corresponding author |
| 245 | _ | _ | |a Platinum recycling going green via induced surface potential alteration enabling fast and efficient dissolution |
| 260 | _ | _ | |a London |c 2016 |b Nature Publishing Group |
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| 520 | _ | _ | |a The recycling of precious metals, for example, platinum, is an essential aspect of sustainability for the modern industry and energy sectors. However, due to its resistance to corrosion, platinum-leaching techniques rely on high reagent consumption and hazardous processes, for example, boiling aqua regia; a mixture of concentrated nitric and hydrochloric acid. Here we demonstrate that complete dissolution of metallic platinum can be achieved by induced surface potential alteration, an ‘electrode-less’ process utilizing alternatively oxidative and reductive gases. This concept for platinum recycling exploits the so-called transient dissolution mechanism, triggered by a repetitive change in platinum surface oxidation state, without using any external electric current or electrodes. The effective performance in non-toxic low-concentrated acid and at room temperature is a strong benefit of this approach, potentially rendering recycling of industrial catalysts, including but not limited to platinum-based systems, more sustainable. |
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| 773 | _ | _ | |a 10.1038/ncomms13164 |g Vol. 7, p. 13164 - |0 PERI:(DE-600)2553671-0 |p 13164 - |t Nature Communications |v 7 |y 2016 |x 2041-1723 |
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