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100 | 1 | _ | |a Redhammer, G. J. |0 P:(DE-HGF)0 |b 0 |e Corresponding author |
245 | _ | _ | |a A single crystal X-ray and powder neutron diffraction study on NASICON-type Li$_{1+x}$Al$_{x}$Ti$_{2−x}$(PO$_{4}$)$_{3}$ (0 ≤ x ≤ 0.5) crystals: Implications on ionic conductivity |
260 | _ | _ | |a Amsterdam [u.a.] |c 2016 |b Elsevier |
336 | 7 | _ | |a article |2 DRIVER |
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336 | 7 | _ | |a Journal Article |b journal |m journal |0 PUB:(DE-HGF)16 |s 1478513914_10743 |2 PUB:(DE-HGF) |
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520 | _ | _ | |a Single crystals of NASICON-type material Li1+xTi2−xAlx(PO4)3 (LATP) with 0 ≤ x ≤ 0.5 were successfully grown using long-term sintering techniques. Sample material was studied by chemical analysis, single crystal X-ray and neutron diffraction. The Ti4+ replacement scales very well with the Al3+ and Li+ incorporation. The additional Li+ thereby enters the M3 cavity of the NASICON framework at x, y, z ∼ (0.07, 0.34, 0.09) and is regarded to be responsible for the enhanced Li+ conduction of LATP as compared to Al-free LTP. Variations in structural parameters, associated with the Ti4+ substitution with Al3+ + Li+ will be discussed in detail in this paper. |
536 | _ | _ | |a 131 - Electrochemical Storage (POF3-131) |0 G:(DE-HGF)POF3-131 |c POF3-131 |f POF III |x 0 |
588 | _ | _ | |a Dataset connected to CrossRef |
700 | 1 | _ | |a Rettenwander, D. |0 0000-0002-2074-941X |b 1 |
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700 | 1 | _ | |a Kumar, C. M. N. |0 P:(DE-HGF)0 |b 4 |
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773 | _ | _ | |a 10.1016/j.solidstatesciences.2016.08.011 |g Vol. 60, p. 99 - 107 |0 PERI:(DE-600)2035101-X |p 99 - 107 |t Solid state sciences |v 60 |y 2016 |x 1293-2558 |
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