000820727 001__ 820727
000820727 005__ 20240619091216.0
000820727 0247_ $$2doi$$a10.1063/1.4966155
000820727 0247_ $$2ISSN$$a0021-9606
000820727 0247_ $$2ISSN$$a1089-7690
000820727 0247_ $$2WOS$$aWOS:000387586200050
000820727 0247_ $$2Handle$$a2128/18974
000820727 037__ $$aFZJ-2016-05995
000820727 082__ $$a540
000820727 1001_ $$0P:(DE-HGF)0$$aKuttich, B.$$b0$$eCorresponding author
000820727 245__ $$aPolymer loaded microemulsions: Changeover from finite size effects to interfacial interactions
000820727 260__ $$aMelville, NY$$bAmerican Institute of Physics$$c2016
000820727 3367_ $$2DRIVER$$aarticle
000820727 3367_ $$2DataCite$$aOutput Types/Journal article
000820727 3367_ $$0PUB:(DE-HGF)16$$2PUB:(DE-HGF)$$aJournal Article$$bjournal$$mjournal$$s1484733886_22334
000820727 3367_ $$2BibTeX$$aARTICLE
000820727 3367_ $$2ORCID$$aJOURNAL_ARTICLE
000820727 3367_ $$00$$2EndNote$$aJournal Article
000820727 520__ $$aForm fluctuations of microemulsion droplets are observed in experiments using dielectric spectroscopy (DS) and neutron spin echo spectroscopy (NSE). Previous work on dioctyl sodium sulfosuccinate based water in oil microemulsions in the droplet phase has shown that adding a water soluble polymer (Polyethylene glycol M = 1500 g mol−1) modifies these fluctuations. While for small droplet sizes (water core radius rc < 37 Å) compared to the size of the polymer both methods consistently showed a reduction in the bending modulus of the surfactant shell as a result of polymer addition, dielectric spectroscopy suggests the opposite behaviour for large droplets. This observation is now confirmed by NSE experiments on large droplets. Structural changes due to polymer addition are qualitatively independent of droplet size. Dynamical properties, however, display a clear variation with the number of polymer chains per droplet, leading to the observed changes in the bending modulus. Furthermore, the contribution of structural and dynamical properties on the changes in bending modulus shifts in weight. With increasing droplet size, we initially find dominating finite size effects and a changeover to a system, where interactions between the confined polymer and the surfactant shell dominate the bending modulus.I. INTRODUCTION
000820727 536__ $$0G:(DE-HGF)POF3-6G15$$a6G15 - FRM II / MLZ (POF3-6G15)$$cPOF3-6G15$$fPOF III$$x0
000820727 536__ $$0G:(DE-HGF)POF3-6G4$$a6G4 - Jülich Centre for Neutron Research (JCNS) (POF3-623)$$cPOF3-623$$fPOF III$$x1
000820727 588__ $$aDataset connected to CrossRef
000820727 65027 $$0V:(DE-MLZ)SciArea-210$$2V:(DE-HGF)$$aSoft Condensed Matter$$x0
000820727 65017 $$0V:(DE-MLZ)GC-1602-2016$$2V:(DE-HGF)$$aPolymers, Soft Nano Particles and  Proteins$$x0
000820727 693__ $$0EXP:(DE-MLZ)J-NSE-20140101$$1EXP:(DE-MLZ)FRMII-20140101$$5EXP:(DE-MLZ)J-NSE-20140101$$6EXP:(DE-MLZ)NL2ao-20140101$$aForschungs-Neutronenquelle Heinz Maier-Leibnitz $$eJ-NSE: Neutron spin-echo spectrometer$$fNL2ao$$x0
000820727 7001_ $$0P:(DE-Juel1)136923$$aIvanova, Oxana$$b1
000820727 7001_ $$0P:(DE-HGF)0$$aGrillo, I.$$b2
000820727 7001_ $$0P:(DE-HGF)0$$aStühn, B.$$b3
000820727 773__ $$0PERI:(DE-600)1473050-9$$a10.1063/1.4966155$$gVol. 145, no. 16, p. 164904 -$$n16$$p164904 - 1-6$$tThe journal of chemical physics$$v145$$x1089-7690$$y2016
000820727 8564_ $$uhttps://juser.fz-juelich.de/record/820727/files/1.4966155.pdf$$yOpenAccess
000820727 8564_ $$uhttps://juser.fz-juelich.de/record/820727/files/1.4966155.gif?subformat=icon$$xicon$$yOpenAccess
000820727 8564_ $$uhttps://juser.fz-juelich.de/record/820727/files/1.4966155.jpg?subformat=icon-180$$xicon-180$$yOpenAccess
000820727 8564_ $$uhttps://juser.fz-juelich.de/record/820727/files/1.4966155.jpg?subformat=icon-700$$xicon-700$$yOpenAccess
000820727 909CO $$ooai:juser.fz-juelich.de:820727$$pdnbdelivery$$pVDB$$pVDB:MLZ$$pdriver$$popen_access$$popenaire
000820727 9101_ $$0I:(DE-588b)5008462-8$$6P:(DE-Juel1)136923$$aForschungszentrum Jülich$$b1$$kFZJ
000820727 9131_ $$0G:(DE-HGF)POF3-6G15$$1G:(DE-HGF)POF3-6G0$$2G:(DE-HGF)POF3-600$$3G:(DE-HGF)POF3$$4G:(DE-HGF)POF$$9G:(DE-HGF)POF3-6G15$$aDE-HGF$$bForschungsbereich Materie$$lGroßgeräte: Materie$$vFRM II / MLZ$$x0
000820727 9131_ $$0G:(DE-HGF)POF3-623$$1G:(DE-HGF)POF3-620$$2G:(DE-HGF)POF3-600$$3G:(DE-HGF)POF3$$4G:(DE-HGF)POF$$9G:(DE-HGF)POF3-6G4$$aDE-HGF$$bForschungsbereich Materie$$lVon Materie zu Materialien und Leben$$vFacility topic: Neutrons for Research on Condensed Matter$$x1
000820727 9141_ $$y2016
000820727 915__ $$0StatID:(DE-HGF)0200$$2StatID$$aDBCoverage$$bSCOPUS
000820727 915__ $$0StatID:(DE-HGF)0600$$2StatID$$aDBCoverage$$bEbsco Academic Search
000820727 915__ $$0StatID:(DE-HGF)0100$$2StatID$$aJCR$$bJ CHEM PHYS : 2015
000820727 915__ $$0StatID:(DE-HGF)0150$$2StatID$$aDBCoverage$$bWeb of Science Core Collection
000820727 915__ $$0StatID:(DE-HGF)0110$$2StatID$$aWoS$$bScience Citation Index
000820727 915__ $$0StatID:(DE-HGF)0111$$2StatID$$aWoS$$bScience Citation Index Expanded
000820727 915__ $$0StatID:(DE-HGF)9900$$2StatID$$aIF < 5
000820727 915__ $$0StatID:(DE-HGF)0510$$2StatID$$aOpenAccess
000820727 915__ $$0StatID:(DE-HGF)0030$$2StatID$$aPeer Review$$bASC
000820727 915__ $$0StatID:(DE-HGF)1150$$2StatID$$aDBCoverage$$bCurrent Contents - Physical, Chemical and Earth Sciences
000820727 915__ $$0StatID:(DE-HGF)0310$$2StatID$$aDBCoverage$$bNCBI Molecular Biology Database
000820727 915__ $$0StatID:(DE-HGF)0420$$2StatID$$aNationallizenz
000820727 915__ $$0StatID:(DE-HGF)0300$$2StatID$$aDBCoverage$$bMedline
000820727 915__ $$0StatID:(DE-HGF)0550$$2StatID$$aNo Authors Fulltext
000820727 915__ $$0StatID:(DE-HGF)0199$$2StatID$$aDBCoverage$$bThomson Reuters Master Journal List
000820727 920__ $$lyes
000820727 9201_ $$0I:(DE-Juel1)JCNS-FRM-II-20110218$$kJCNS (München) ; Jülich Centre for Neutron Science JCNS (München) ; JCNS-FRM-II$$lJCNS-FRM-II$$x0
000820727 9201_ $$0I:(DE-Juel1)JCNS-1-20110106$$kNeutronenstreuung ; JCNS-1$$lNeutronenstreuung $$x1
000820727 980__ $$ajournal
000820727 980__ $$aVDB
000820727 980__ $$aUNRESTRICTED
000820727 980__ $$aI:(DE-Juel1)JCNS-FRM-II-20110218
000820727 980__ $$aI:(DE-Juel1)JCNS-1-20110106
000820727 9801_ $$aFullTexts