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@ARTICLE{Hockun:820908,
author = {Hockun, Katja and Mollenhauer, Gesine and Ho, Sze Ling and
Hefter, Jens and Ohlendorf, Christian and Zolitschka, Bernd
and Mayr, Christoph and Lücke, Andreas and Schefuß, Enno},
title = {{U}sing distributions and stable isotopes of n-alkanes to
disentangle organic matter contributions to sediments of
{L}aguna {P}otrok {A}ike, {A}rgentina},
journal = {Organic geochemistry},
volume = {102},
issn = {0146-6380},
address = {Amsterdam [u.a.]},
publisher = {Elsevier Science},
reportid = {FZJ-2016-06172},
pages = {110–119},
year = {2016},
abstract = {When using biomarkers such as n-alkanes as tools for
paleo-environmental reconstructions, it is imperative to
determine their specific sources for each setting. Toward
that goal, we analyzed a set of various potential organic
matter (OM) sources such as aquatic and terrestrial plants,
dust, and soils from Laguna Potrok Aike (LPA) and
surrounding areas in southern Patagonia. We determined chain
length distributions and hydrogen (δD) and carbon (δ13C)
isotopic compositions of n-alkanes of different OM sources
in order to quantify their relative contributions to lake
sediments. Our results reveal that the mid-chain n-alkane,
n-C23, is predominantly produced by submerged aquatic
plants, whereas long-chain n-alkanes (n-C29–n-C31) are
derived from various terrestrial sources. We estimated their
relative contributions to the sediment using two approaches,
i.e., based on the n-alkane distributions and their δD and
δ13C values. Both approaches result in similar estimates of
aquatic and terrestrial contributions for mid- and
long-chain n-alkanes to the sediment. $62–73\%$ of the
mid-chain n-C23 alkanes originate from aquatic sources while
$66–77\%$ of the long-chain n-alkanes originate from dust
and $14–30\%$ from terrestrial plants. Our study shows
that mid-chain n-alkanes such as the n-C23 alkane in LPA are
derived mainly from aquatic macrophytes and thus have the
potential to record changes in lake-water isotopic
composition. In contrast, the n-C29 alkane reflects the
isotopic signal of various terrestrial sources from southern
Patagonia.},
cin = {IBG-3},
ddc = {540},
cid = {I:(DE-Juel1)IBG-3-20101118},
pnm = {255 - Terrestrial Systems: From Observation to Prediction
(POF3-255)},
pid = {G:(DE-HGF)POF3-255},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000392534300011},
doi = {10.1016/j.orggeochem.2016.10.001},
url = {https://juser.fz-juelich.de/record/820908},
}