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@ARTICLE{Schfer:824108,
author = {Schäfer, Dominique and Weiß, Philipp and Ermert, Johannes
and Castillo, Johnny and Zarrad, Fadi and Neumaier, Bernd},
title = {{P}reparation of {N}o-{C}arrier-{A}dded 6-[$^{18}$
{F}]{F}luoro- l -tryptophan via {C}u-{M}ediated
{R}adiofluorination},
journal = {European journal of organic chemistry},
volume = {2016},
number = {27},
issn = {1434-193X},
address = {Weinheim},
publisher = {Wiley-VCH Verl.},
reportid = {FZJ-2016-06732},
pages = {4621 - 4628},
year = {2016},
abstract = {18F-Labeled aromatic amino acids exhibit great potential
for diagnostic applications using positron emission
tomography. However, the introduction of 18F into aromatic
compounds remains challenging, and novel fluorination
methods facilitating easy access to 18F-labeled arenes are
highly sought after. In recent years, novel metal-mediated
fluorination methods have been reported and transferred into
radiochemistry. Based on Cu-mediated radiofluorination, a
two-step synthesis of no-carrier-added (n.c.a.)
6-[18F]fluoro-l-tryptophan was developed.
6-[18F]Fluoro-l-tryptophan was synthesized with an overall
radochemical yield of $16 ± 4\%$ within 110 min and a
specific activity of 280 GBq µmol–1. The radiochemical
purity was more than $99 \%.$ The developed method allowed
access to radiofluorinated tryptophan derivatives in high
radiochemical yields and opens new ways to provide
radiofluorinated amino acids. Furthermore, the reaction
conditions were optimized to facilitate automation.},
cin = {INM-5},
ddc = {540},
cid = {I:(DE-Juel1)INM-5-20090406},
pnm = {573 - Neuroimaging (POF3-573)},
pid = {G:(DE-HGF)POF3-573},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000384549600005},
doi = {10.1002/ejoc.201600705},
url = {https://juser.fz-juelich.de/record/824108},
}