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@ARTICLE{Weber:824284,
author = {Weber, Andreas and Stühn, Bernd},
title = {{S}tructure and phase behavior of polymer loaded non-ionic
and anionic microemulsions},
journal = {The journal of chemical physics},
volume = {144},
number = {14},
issn = {1089-7690},
address = {Melville, NY},
publisher = {American Institute of Physics},
reportid = {FZJ-2016-06903},
pages = {144903 -},
year = {2016},
abstract = {We investigate the structure and phase behavior of C12E4
based reverse water in octane microemulsions with small
angle x-ray scattering and small angle neutron scattering
experiments to explore the phase diagram of the
dropletstructure. In the regime of stable droplets, these
droplets are loaded with the hydrophilic polymer
polyethyleneoxide (MW = 1500 g/mol) and compared with
microemulsions based on the anionic surfactant AOT. In the
small angle neutron scattering experiments, we use shell
contrast to focus on the surfactant shell and its variation
with addition of polymer. We observe, as predicted by
indirect measurements such as dielectric spectroscopy, that
the polymer interacts differently with a nonionic or an
anionic surfactant shell: In the former case the addition of
polymer does not seem to affect the surfactant shell. In the
latter case, the obtained scattering data show that the
anionic surfactant layer is strongly influenced leading to a
higher polydispersity which may be attributed to a floppier
surfactant shell.},
cin = {JCNS (München) ; Jülich Centre for Neutron Science JCNS
(München) ; JCNS-FRM-II / Neutronenstreuung ; JCNS-1 /
ICS-1},
ddc = {540},
cid = {I:(DE-Juel1)JCNS-FRM-II-20110218 /
I:(DE-Juel1)JCNS-1-20110106 / I:(DE-Juel1)ICS-1-20110106},
pnm = {6G4 - Jülich Centre for Neutron Research (JCNS)
(POF3-623)},
pid = {G:(DE-HGF)POF3-6G4},
experiment = {EXP:(DE-MLZ)KWS1-20140101},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000374774000049},
doi = {10.1063/1.4945610},
url = {https://juser.fz-juelich.de/record/824284},
}