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100 1 _ |a Teucher, Georg
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245 _ _ |a Processing of Al-doped ZnO protective thin films on aluminum current collectors for lithium ion batteries
260 _ _ |a Amsterdam [u.a.]
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520 _ _ |a In this work, aluminum current collectors for Li-ion batteries were coated with protection layers made of Al-doped ZnO (ZnO:Al) to prevent the corrosion of aluminum caused by bis(trifluoromethylsulfonyl)imide (TFSI−) at 5 V. These thin films of ~ 100 nm thickness were prepared with a facile and scalable sol-gel coating process with subsequent heat treatment by rapid thermal processing (RTP) at 500 °C. The ZnO:Al films exhibited the usual hexagonal phase, a homogeneous morphology and a sufficient electronic conductivity. In electrochemical testing, chronoamperometry demonstrated that the protection layer reduces the corrosion of the aluminum current collector 120 times compared with conventional unprotected aluminum.
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700 1 _ |a Van Gestel, Tim
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700 1 _ |a Krott, Manuel
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700 1 _ |a Gehrke, Hans-Gregor
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700 1 _ |a Eichel, Rüdiger-A.
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700 1 _ |a Uhlenbruck, Sven
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