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@ARTICLE{Berger:824587,
      author       = {Berger, Cornelius and Mahmoud, Abdelfattah and Hermann,
                      Raphael and Braun, Waldemar and Yazhenskikh, Elena and Sohn,
                      Yoo Jung and Menzler, Norbert H. and Guillon, Olivier and
                      Bram, Martin},
      title        = {{C}alcium-{I}ron {O}xide as {E}nergy {S}torage {M}edium in
                      {R}echargeable {O}xide {B}atteries},
      journal      = {Journal of the American Ceramic Society},
      volume       = {99},
      number       = {12},
      issn         = {0002-7820},
      address      = {Oxford [u.a.]},
      publisher    = {Wiley-Blackwell},
      reportid     = {FZJ-2016-07154},
      pages        = {4083-4092},
      year         = {2016},
      abstract     = {Rechargeable oxide batteries (ROB) comprise a regenerative
                      solid oxide cell (rSOC) and a storage medium for oxygen
                      ions. A sealed ROB avoids pumping loss, heat loss, and gas
                      purity expenses in comparison with conventional rSOC.
                      However, the iron oxide base storage medium degrades during
                      charging–discharging cycles. In comparison, CaFe3O5 has
                      improved cyclability and a high reversible oxygen storage
                      capacity of 22.3 $mol\%.$ In this study, we analyzed the
                      redox mechanism of this compound. After a solid-state
                      synthesis of CaFe3O5, we verified the phase composition and
                      studied the redox reaction by means of X-ray diffraction,
                      Mössbauer spectrometry, and scanning electron microscopy.
                      Results show a great potential to operate the battery with
                      this storage material during multiple charging–discharging
                      cycles.},
      cin          = {IEK-1 / JCNS-2 / IEK-2 / PGI-4 / JARA-ENERGY / JARA-FIT},
      ddc          = {660},
      cid          = {I:(DE-Juel1)IEK-1-20101013 / I:(DE-Juel1)JCNS-2-20110106 /
                      I:(DE-Juel1)IEK-2-20101013 / I:(DE-Juel1)PGI-4-20110106 /
                      $I:(DE-82)080011_20140620$ / $I:(DE-82)080009_20140620$},
      pnm          = {135 - Fuel Cells (POF3-135) / SOFC - Solid Oxide Fuel Cell
                      (SOFC-20140602) / 144 - Controlling Collective States
                      (POF3-144) / 524 - Controlling Collective States (POF3-524)
                      / 6212 - Quantum Condensed Matter: Magnetism,
                      Superconductivity (POF3-621) / 6213 - Materials and
                      Processes for Energy and Transport Technologies (POF3-621) /
                      6G4 - Jülich Centre for Neutron Research (JCNS) (POF3-623)
                      / HITEC - Helmholtz Interdisciplinary Doctoral Training in
                      Energy and Climate Research (HITEC) (HITEC-20170406)},
      pid          = {G:(DE-HGF)POF3-135 / G:(DE-Juel1)SOFC-20140602 /
                      G:(DE-HGF)POF3-144 / G:(DE-HGF)POF3-524 /
                      G:(DE-HGF)POF3-6212 / G:(DE-HGF)POF3-6213 /
                      G:(DE-HGF)POF3-6G4 / G:(DE-Juel1)HITEC-20170406},
      typ          = {PUB:(DE-HGF)16},
      UT           = {WOS:000393844100032},
      doi          = {10.1111/jace.14439},
      url          = {https://juser.fz-juelich.de/record/824587},
}