% IMPORTANT: The following is UTF-8 encoded. This means that in the presence
% of non-ASCII characters, it will not work with BibTeX 0.99 or older.
% Instead, you should use an up-to-date BibTeX implementation like “bibtex8” or
% “biber”.
@ARTICLE{Monkenbusch:824659,
author = {Monkenbusch, M. and Krutyeva, M. and Pyckhout-Hintzen, W.
and Antonius, W. and Hövelmann, C. H. and Allgaier, J. and
Brás, A. and Farago, B. and Wischnewski, A. and Richter,
D.},
title = {{M}olecular {V}iew on {S}upramolecular {C}hain and
{A}ssociation {D}ynamics},
journal = {Physical review letters},
volume = {117},
number = {14},
issn = {1079-7114},
address = {College Park, Md.},
publisher = {APS},
reportid = {FZJ-2016-07222},
pages = {147802},
year = {2016},
abstract = {The chain and association dynamics of supramolecular
polymer ensembles decisively determines their properties.
Using neutron spin echo (NSE) spectroscopy we present
molecular insight into the space and time evolution of this
dynamics. Studying a well characterized ensemble of linearly
associating telechelic poly(ethylene glycol) melts carrying
triple H-bonding end groups, we show that H-bond breaking
significantly impacts the mode spectrum of the associates.
The breaking affects the mode contributions and not the
relaxation times as was assumed previously. NSE spectra
directly reveal the so far intangible H-bond lifetimes in
the supramolecular melt and demonstrate that for both the
microscopic and the macroscopic dynamics of the
supramolecular ensemble the instantaneous average of the Mw
distribution governs the system response at least as long as
the Rouse picture applies.},
cin = {JCNS-1},
ddc = {550},
cid = {I:(DE-Juel1)JCNS-1-20110106},
pnm = {6G4 - Jülich Centre for Neutron Research (JCNS) (FZJ)
(POF4-6G4) / 633 - Life Sciences – Building Blocks of
Life: Structure and Function (POF4-633) / 5251 - Multilevel
Brain Organization and Variability (POF4-525) / 5241 -
Molecular Information Processing in Cellular Systems
(POF4-524)},
pid = {G:(DE-HGF)POF4-6G4 / G:(DE-HGF)POF4-633 /
G:(DE-HGF)POF4-5251 / G:(DE-HGF)POF4-5241},
typ = {PUB:(DE-HGF)16},
pubmed = {27740839},
UT = {WOS:000384082500027},
doi = {10.1103/PhysRevLett.117.147802},
url = {https://juser.fz-juelich.de/record/824659},
}