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000824774 1001_ $$0P:(DE-Juel1)161141$$aYu, Shicheng$$b0$$eCorresponding author
000824774 245__ $$aMorphology Dependency of Li$_{3}$V$_{2}$(PO$_{4}$)$_{3}$/C Cathode Material Regarding to Rate Capability and Cycle Life in Lithium-Ion Batteries
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000824774 520__ $$aTransition-metal phosphates have been extensively studied as potential electrode materials for lithium-ion batteries. For this application, high rate capability and cycling performance are required. In this work, we present a one-pot solvothermal synthesis process in combination with in situ carbonization for the tailoring of Li3V2(PO4)3/C morphologies with improvements of the electrochemical performance. These include an unstructured cluster, a needle-like microstructure, a flake-like microstructure and a hollowsphere microstructure. We demonstrate a significant impact of the particle morphology with respect to the electrochemical performance. The results obtained include, for instance, needle-like Li3V2(PO4)3/C showing a superior rate capability of about 72% (∼96 mAh g−1) of its theoretical capacity being maintained at 30 C, whereas the flake-like Li3V2(PO4)3/C exhibits outstanding cycling performance with a capacity retention of 97.1% (∼112 mAh g−1) of its initial capacity after 1000 cycles at 2 C. Our work demonstrates that the morphology of cathode particles defines a highly selective parameter to improve the electrochemical properties. Accordingly, strategies to selectively tailor particle morphology for a given application become feasible.
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000824774 7001_ $$0P:(DE-Juel1)166415$$aMertens, Andreas$$b1
000824774 7001_ $$0P:(DE-Juel1)161208$$aTempel, Hermann$$b2
000824774 7001_ $$0P:(DE-Juel1)156123$$aEichel, Rüdiger-A.$$b3
000824774 7001_ $$0P:(DE-Juel1)157700$$aKungl, Hans$$b4
000824774 7001_ $$0P:(DE-Juel1)161348$$aSchierholz, Roland$$b5
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