TY  - JOUR
AU  - Woolfson, R. J.
AU  - Timco, G. A.
AU  - Chiesa, A.
AU  - Vitorica-Yrezabal, I. J.
AU  - Tuna, F.
AU  - Guidi, T.
AU  - Pavarini, Eva
AU  - Santini, P.
AU  - Carretta, S.
AU  - Winpenny, R. E. P.
TI  - [CrF(O$_{2}$C$^{t}$Bu)$_{2}$]$_{9}$: Synthesis and Characterization of a Regular Homometallic Ring with an Odd Number of Metal Centers and Electrons
JO  - Angewandte Chemie / International edition
VL  - 55
SN  - 0044-8249
CY  - Weinheim
PB  - Wiley-VCH
M1  - FZJ-2016-07385
SP  - 8856
PY  - 2016
AB  - The first regular homometallic ring containing an odd number of metal centers is reported. The ring was synthesized by means of amine‐templated self‐assembly. Extensive physical characterization studies, including magnetic measurements, powder inelastic neutron scattering (INS), and DFT calculations, show that the molecule has a near perfect match to the expected behavior for a frustrated system with the lowest energy pair of S=1/2 spin states separated by only 0.1 meV (0.8 cm−1)
LB  - PUB:(DE-HGF)16
UR  - <Go to ISI:>//WOS:000383253700007
C6  - pmid:27294807
DO  - DOI:10.1002/anie.201601734
UR  - https://juser.fz-juelich.de/record/824883
ER  -