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@ARTICLE{Woolfson:824883,
author = {Woolfson, R. J. and Timco, G. A. and Chiesa, A. and
Vitorica-Yrezabal, I. J. and Tuna, F. and Guidi, T. and
Pavarini, Eva and Santini, P. and Carretta, S. and Winpenny,
R. E. P.},
title = {[{C}r{F}({O}$_{2}${C}$^{t}${B}u)$_{2}$]$_{9}$: {S}ynthesis
and {C}haracterization of a {R}egular {H}omometallic {R}ing
with an {O}dd {N}umber of {M}etal {C}enters and {E}lectrons},
journal = {Angewandte Chemie / International edition},
volume = {55},
issn = {0044-8249},
address = {Weinheim},
publisher = {Wiley-VCH},
reportid = {FZJ-2016-07385},
pages = {8856},
year = {2016},
abstract = {The first regular homometallic ring containing an odd
number of metal centers is reported. The ring was
synthesized by means of amine‐templated self‐assembly.
Extensive physical characterization studies, including
magnetic measurements, powder inelastic neutron scattering
(INS), and DFT calculations, show that the molecule has a
near perfect match to the expected behavior for a frustrated
system with the lowest energy pair of S=1/2 spin states
separated by only 0.1 meV (0.8 cm−1)},
cin = {IAS-3},
ddc = {540},
cid = {I:(DE-Juel1)IAS-3-20090406},
pnm = {144 - Controlling Collective States (POF3-144)},
pid = {G:(DE-HGF)POF3-144},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000383253700007},
pubmed = {pmid:27294807},
doi = {10.1002/anie.201601734},
url = {https://juser.fz-juelich.de/record/824883},
}