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@ARTICLE{Jin:824884,
author = {Jin, Xiao-Wei and Lu, Lu and Mi, Shao-Bo and Cheng, Sheng
and Liu, Ming and Jia, Chun-Lin},
title = {{A}tomic scale {I}nvestigation of planar defects in
0.95{N}a$_{0.5}${B}i$_{0.5}${T}i{O}$_{3}$-0.05{B}a{T}i{O}$_{3}$
thin films on {S}r{T}i{O}$_{3}$ (001) substrates},
journal = {Journal of alloys and compounds},
volume = {676},
issn = {0925-8388},
address = {Lausanne},
publisher = {Elsevier},
reportid = {FZJ-2016-07386},
pages = {173 -180},
year = {2016},
abstract = {Thin films of lead-free piezoelectric
0.95Na0.5Bi0.5TiO3–0.05BaTiO3 (0.95NBT–0.05BT) are
epitaxially grown on single crystalline SrTiO3 (001)
substrates at 800 °C, 850 °C and 900 °C, respectively, by
a high-pressure sputtering deposition technique. The
microstructure of the thin films is investigated by means of
aberration-corrected scanning transmission electron
microscopy. Planar defects are observed and the density of
the defects increases with the increase of the film-growth
temperature. Two types of planar defects in the films are
studied at the atomic scale. One consists of groups of
edge-sharing TiO6 octahedra with Bi atoms located between
the TiO6 octahedral groups, and the other exists in the form
of Na/Bi(Ba)single bondO2single bondNa/Bi(Ba) layer parallel
to the (010) plane of the films. Based on the structure
feature of the planar defects, the propagation of the planar
defects related to edge-sharing TiO6 octahedra within the
films and from the film-substrate interface is discussed.
Furthermore, the ordering of the planar defects is expected
to form new structures. In comparison with the
microstructure of 0.95NBT–0.05BT bulk materials, the
appearance of the high-density planar defects observed
within the films could be considered to be responsible for
the difference in the physical properties between the bulk
materials and the films.},
cin = {PGI-5},
ddc = {670},
cid = {I:(DE-Juel1)PGI-5-20110106},
pnm = {143 - Controlling Configuration-Based Phenomena (POF3-143)},
pid = {G:(DE-HGF)POF3-143},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000374328100024},
doi = {10.1016/j.jallcom.2016.03.120},
url = {https://juser.fz-juelich.de/record/824884},
}