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@ARTICLE{Meusel:824994,
author = {Meusel, Hannah and Kuhn, Uwe and Reiffs, Andreas and
Mallik, Chinmay and Harder, Hartwig and Martinez, Monica and
Schuladen, Jan and Bohn, Birger and Parchatka, Uwe and
Crowley, John N. and Fischer, Horst and Tomsche, Laura and
Novelli, Anna and Hoffmann, Thorsten and Janssen, Ruud H. H.
and Hartogensis, Oscar and Pikridas, Michael and Vrekoussis,
Mihalis and Bourtsoukidis, Efstratios and Weber, Bettina and
Lelieveld, Jos and Williams, Jonathan and Pöschl, Ulrich
and Cheng, Yafang and Su, Hang},
title = {{D}aytime formation of nitrous acid at a coastal remote
site in {C}yprus indicating a common ground source of
atmospheric {HONO} and {NO}},
journal = {Atmospheric chemistry and physics},
volume = {16},
number = {22},
issn = {1680-7324},
address = {Katlenburg-Lindau},
publisher = {EGU},
reportid = {FZJ-2016-07490},
pages = {14475 - 14493},
year = {2016},
abstract = {Characterization of daytime sources of nitrous acid (HONO)
is crucial to understand atmospheric oxidation and radical
cycling in the planetary boundary layer. HONO and numerous
other atmospheric trace constituents were measured on the
Mediterranean island of Cyprus during the CYPHEX (CYprus
PHotochemical EXperiment) campaign in summer 2014. Average
volume mixing ratios of HONO were 35 pptv (±25 pptv)
with a HONO ∕ NOx ratio of 0.33, which was
considerably higher than reported for most other rural and
urban regions. Diel profiles of HONO showed peak values in
the late morning (60 ± 28 pptv around 09:00 local
time) and persistently high mixing ratios during daytime
(45 ± 18 pptv), indicating that the photolytic loss
of HONO is compensated by a strong daytime source. Budget
analyses revealed unidentified sources producing up to
3.4 × 106 molecules cm−3 s−1 of HONO
and up to 2.0 × 107 molecules cm−3 s−1
NO. Under humid conditions (relative
$humidity > 70 \%),$ the source strengths of
HONO and NO exhibited a close linear correlation
(R2 = 0.72), suggesting a common source that may be
attributable to emissions from microbial communities on soil
surfaces.},
cin = {IEK-8},
ddc = {550},
cid = {I:(DE-Juel1)IEK-8-20101013},
pnm = {243 - Tropospheric trace substances and their
transformation processes (POF3-243)},
pid = {G:(DE-HGF)POF3-243},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000388187800003},
doi = {10.5194/acp-16-14475-2016},
url = {https://juser.fz-juelich.de/record/824994},
}