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@ARTICLE{Warner:825421,
author = {Warner, Ben and El Hallak, Fadi and Atodiresei, Nicolae and
Seibt, Philipp and Prüser, Henning and Caciuc, Vasile and
Waters, Michael and Fisher, Andrew J. and Blügel, Stefan
and van Slageren, Joris and Hirjibehedin, Cyrus F.},
title = {{S}ub-molecular modulation of a 4f driven {K}ondo resonance
by surface-induced asymmetry},
journal = {Nature Communications},
volume = {7},
issn = {2041-1723},
address = {London},
publisher = {Nature Publishing Group},
reportid = {FZJ-2016-07884},
pages = {12785},
year = {2016},
abstract = {Coupling between a magnetic impurity and an external bath
can give rise to many-body quantum phenomena, including
Kondo and Hund’s impurity states in metals, and
Yu-Shiba-Rusinov states in superconductors. While advances
have been made in probing the magnetic properties of d-shell
impurities on surfaces, the confinement of f orbitals makes
them difficult to access directly. Here we show that a 4f
driven Kondo resonance can be modulated spatially by
asymmetric coupling between a metallic surface and a
molecule containing a 4f-like moment. Strong hybridization
of dysprosium double-decker phthalocyanine with Cu(001)
induces Kondo screening of the central magnetic moment.
Misalignment between the symmetry axes of the molecule and
the surface induces asymmetry in the molecule’s electronic
structure, spatially mediating electronic access to the
magnetic moment through the Kondo resonance. This work
demonstrates the important role that molecular ligands have
in mediating electronic and magnetic coupling and in
accessing many-body quantum states.},
cin = {IAS-1 / PGI-1 / JARA-FIT / JARA-HPC},
ddc = {500},
cid = {I:(DE-Juel1)IAS-1-20090406 / I:(DE-Juel1)PGI-1-20110106 /
$I:(DE-82)080009_20140620$ / $I:(DE-82)080012_20140620$},
pnm = {142 - Controlling Spin-Based Phenomena (POF3-142) / 143 -
Controlling Configuration-Based Phenomena (POF3-143)},
pid = {G:(DE-HGF)POF3-142 / G:(DE-HGF)POF3-143},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000385256500015},
pubmed = {pmid:27666413},
doi = {10.1038/ncomms12785},
url = {https://juser.fz-juelich.de/record/825421},
}