000825422 001__ 825422 000825422 005__ 20210129225321.0 000825422 0247_ $$2doi$$a10.1021/acsnano.6b05819 000825422 0247_ $$2ISSN$$a1936-0851 000825422 0247_ $$2ISSN$$a1936-086X 000825422 0247_ $$2WOS$$aWOS:000391079700045 000825422 037__ $$aFZJ-2016-07885 000825422 082__ $$a540 000825422 1001_ $$0P:(DE-HGF)0$$aFarwick zum Hagen, Ferdinand H.$$b0 000825422 245__ $$aStructure and Growth of Hexagonal Boron Nitride on Ir(111) 000825422 260__ $$aWashington, DC$$bSoc.$$c2016 000825422 3367_ $$2DRIVER$$aarticle 000825422 3367_ $$2DataCite$$aOutput Types/Journal article 000825422 3367_ $$0PUB:(DE-HGF)16$$2PUB:(DE-HGF)$$aJournal Article$$bjournal$$mjournal$$s1483606506_4020 000825422 3367_ $$2BibTeX$$aARTICLE 000825422 3367_ $$2ORCID$$aJOURNAL_ARTICLE 000825422 3367_ $$00$$2EndNote$$aJournal Article 000825422 520__ $$aUsing the X-ray standing wave method, scanning tunneling microscopy, low energy electron diffraction, and density functional theory, we precisely determine the lateral and vertical structure of hexagonal boron nitride on Ir(111). The moiré superstructure leads to a periodic arrangement of strongly chemisorbed valleys in an otherwise rather flat, weakly physisorbed plane. The best commensurate approximation of the moiré unit cell is (12 × 12) boron nitride cells resting on (11 × 11) substrate cells, which is at variance with several earlier studies. We uncover the existence of two fundamentally different mechanisms of layer formation for hexagonal boron nitride, namely, nucleation and growth as opposed to network formation without nucleation. 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